Manganese oxide promoter effects in the copper-catalyzed hydrogenation of ethyl acetate
[Display omitted] •A method was developed to tune the MnOx-Cu particle size on graphitic carbon.•The MnOx-Cu particle size was around 6 nm, using 8 wt% Cu and between 0 and 3.4 wt% Mn.•The hydrogenation activity increased 7-fold when using 11 mol% Mn/(Cu + Mn) versus pure Cu.•Apparent activation ene...
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| Published in: | Journal of catalysis Vol. 394; pp. 307 - 315 |
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01-02-2021
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| Abstract | [Display omitted]
•A method was developed to tune the MnOx-Cu particle size on graphitic carbon.•The MnOx-Cu particle size was around 6 nm, using 8 wt% Cu and between 0 and 3.4 wt% Mn.•The hydrogenation activity increased 7-fold when using 11 mol% Mn/(Cu + Mn) versus pure Cu.•Apparent activation energy decreased from ~100 (pure Cu) to 52 kJ mol−1 for 11 mol% Mn/(Cu + Mn).•Increasing the water concentration decreased the catalyst activity, yet less for MnOx-promoted Cu.
Supported metal catalysts are widely used in the chemical industry, commonly with added metal oxide promoters to enhance the catalytic performance. Here, we discuss manganese oxide as an efficient promoter for the Cu-based hydrogenation of ethyl acetate; a model hydrogenation reaction. A series of carbon-supported MnOx-Cu catalysts was prepared with 6 nm MnOx-Cu particles, while varying the Mn loading between 0 and 33 mol% Mn/(Cu + Mn), without changing the Cu loading or support structure. At temperatures of 180–210 °C and 30 bar pressure, the addition of 11 mol% Mn to Cu gave a 7-fold enhancement in activity, and better catalyst stability. Furthermore, the apparent activation energy decreased from ~100 to 50 kJ mol−1. State-of-the-art characterization allowed to establish a correlation between catalyst structure and performance. |
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| AbstractList | [Display omitted]
•A method was developed to tune the MnOx-Cu particle size on graphitic carbon.•The MnOx-Cu particle size was around 6 nm, using 8 wt% Cu and between 0 and 3.4 wt% Mn.•The hydrogenation activity increased 7-fold when using 11 mol% Mn/(Cu + Mn) versus pure Cu.•Apparent activation energy decreased from ~100 (pure Cu) to 52 kJ mol−1 for 11 mol% Mn/(Cu + Mn).•Increasing the water concentration decreased the catalyst activity, yet less for MnOx-promoted Cu.
Supported metal catalysts are widely used in the chemical industry, commonly with added metal oxide promoters to enhance the catalytic performance. Here, we discuss manganese oxide as an efficient promoter for the Cu-based hydrogenation of ethyl acetate; a model hydrogenation reaction. A series of carbon-supported MnOx-Cu catalysts was prepared with 6 nm MnOx-Cu particles, while varying the Mn loading between 0 and 33 mol% Mn/(Cu + Mn), without changing the Cu loading or support structure. At temperatures of 180–210 °C and 30 bar pressure, the addition of 11 mol% Mn to Cu gave a 7-fold enhancement in activity, and better catalyst stability. Furthermore, the apparent activation energy decreased from ~100 to 50 kJ mol−1. State-of-the-art characterization allowed to establish a correlation between catalyst structure and performance. |
| Author | Visser, Nienke L. de Jongh, Petra E. van der Hoeven, Jessi E.S. de Jong, Krijn P. Beerthuis, Rolf Ngene, Peter Deeley, Jon M.S. Sunley, Glenn J. |
| Author_xml | – sequence: 1 givenname: Rolf surname: Beerthuis fullname: Beerthuis, Rolf organization: Inorganic Chemistry and Catalysis, Debye Institute for Nanomaterials Science, Utrecht University, Universiteitsweg 99, 3584 CG Utrecht, the Netherlands – sequence: 2 givenname: Nienke L. orcidid: 0000-0003-1027-2299 surname: Visser fullname: Visser, Nienke L. organization: Inorganic Chemistry and Catalysis, Debye Institute for Nanomaterials Science, Utrecht University, Universiteitsweg 99, 3584 CG Utrecht, the Netherlands – sequence: 3 givenname: Jessi E.S. surname: van der Hoeven fullname: van der Hoeven, Jessi E.S. organization: Inorganic Chemistry and Catalysis, Debye Institute for Nanomaterials Science, Utrecht University, Universiteitsweg 99, 3584 CG Utrecht, the Netherlands – sequence: 4 givenname: Peter orcidid: 0000-0003-3691-0623 surname: Ngene fullname: Ngene, Peter organization: Inorganic Chemistry and Catalysis, Debye Institute for Nanomaterials Science, Utrecht University, Universiteitsweg 99, 3584 CG Utrecht, the Netherlands – sequence: 5 givenname: Jon M.S. orcidid: 0000-0002-9322-6468 surname: Deeley fullname: Deeley, Jon M.S. organization: Applied Chemistry and Physics Centre of Expertise, BP Group Research, Hull Research and Technology Centre, c/o BP Chemicals, Saltend, Hull, United Kingdom – sequence: 6 givenname: Glenn J. orcidid: 0000-0001-6751-6886 surname: Sunley fullname: Sunley, Glenn J. organization: Applied Chemistry and Physics Centre of Expertise, BP Group Research, Hull Research and Technology Centre, c/o BP Chemicals, Saltend, Hull, United Kingdom – sequence: 7 givenname: Krijn P. surname: de Jong fullname: de Jong, Krijn P. organization: Inorganic Chemistry and Catalysis, Debye Institute for Nanomaterials Science, Utrecht University, Universiteitsweg 99, 3584 CG Utrecht, the Netherlands – sequence: 8 givenname: Petra E. surname: de Jongh fullname: de Jongh, Petra E. email: P.E.deJongh@uu.nl organization: Inorganic Chemistry and Catalysis, Debye Institute for Nanomaterials Science, Utrecht University, Universiteitsweg 99, 3584 CG Utrecht, the Netherlands |
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| Keywords | Promoter Water Heterogeneous catalysis Copper Hydrogenation Carbon Manganese |
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•A method was developed to tune the MnOx-Cu particle size on graphitic carbon.•The MnOx-Cu particle size was around 6 nm, using 8 wt% Cu and... |
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| Title | Manganese oxide promoter effects in the copper-catalyzed hydrogenation of ethyl acetate |
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