Highly active homoleptic nickel(II) bis-N-heterocyclic carbene catalyst for Suzuki–Miyaura and Heck cross-coupling reactions

Highly active homoleptic nickel(II) bis-N-heterocyclic carbene catalyst for Suzuki–Miyaura and Heck cross-coupling reactions

Highly active homoleptic nickel(II) bis-N-heterocyclic carbene catalyst for Suzuki–Miyaura and Heck cross-coupling reactions are reported. [Display omitted] New homoleptic nickel(II) biscarbene complex was synthesized and structurally characterized. The complex depicted the excellent catalytic activ...

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Bibliographic Details
Published in:Polyhedron Vol. 158; pp. 125 - 134
Main Authors: Nirmala, Muthukumaran, Arruri, Sathyanarayana, Vaddamanu, Moulali, Karupnaswamy, Ramesh, Mannarsamy, Maruthupandi, Adinarayana, Mannem, Ganesan, Prabusankar
Format: Journal Article
Language:English
Published: Elsevier Ltd 15-01-2019
Subjects:
Carbene
Catalysis
Heck
Nickel(II)
Suzuki-Miyaura
Carbene
Catalysis
Suzuki-Miyaura
Nickel(II)
Heck
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Summary:Highly active homoleptic nickel(II) bis-N-heterocyclic carbene catalyst for Suzuki–Miyaura and Heck cross-coupling reactions are reported. [Display omitted] New homoleptic nickel(II) biscarbene complex was synthesized and structurally characterized. The complex depicted the excellent catalytic activities with only 3 mol% catalyst loading along with wide substrate scope for the Suzuki–Miyaura cross-coupling reactions (twenty six examples) and Heck coupling reactions (eighteen examples).
ISSN:0277-5387
DOI:10.1016/j.poly.2018.10.028