Hybrid capacitive deionization with Ag coated carbon composite electrode

Capacitive deionization (CDI) using capacitive electrodes is highlighted as an alternative desalination technology because of its advantages of low cost and high energy-efficiency. However, the deionization capacity of CDI is somewhat limited because its capacity relies on the double layer capacitan...

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Published in:Desalination Vol. 422; pp. 42 - 48
Main Authors: Yoon, Hongsik, Lee, Jaehan, Kim, Seonghwan, Yoon, Jeyong
Format: Journal Article
Language:English
Published: Elsevier B.V 15-11-2017
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Abstract Capacitive deionization (CDI) using capacitive electrodes is highlighted as an alternative desalination technology because of its advantages of low cost and high energy-efficiency. However, the deionization capacity of CDI is somewhat limited because its capacity relies on the double layer capacitance of a carbon electrode. Thus, improving the deionization capacity of a CDI system is one of the most urgent issues in CDI technology. Herein, Ag coated carbon composite electrode employed hybrid CDI system (Ag coated HCDI) was investigated to enhance the deionization performances. The Ag coated carbon composite electrode was made by coating a small amount of Ag onto a carbon capacitive electrode, exhibiting the characteristics of a battery and a capacitor together. As major results, the CDI deionization capacity (88% more), rate (39% more), and charge efficiency (76%➔92%) was dramatically enhanced due to the Ag coating. The significant improvement in deionization performance is explained by the enhanced specific capacity combining the capacitance in the carbon electrode with the Ag mediated charge transfer reaction. In addition, the Ag coated HCDI (73.3kJmole−1) is superior to membrane assisted CDI (136.7kJmole−1) in terms of energy consumption for deionization due to its low voltage feasible operation. [Display omitted] •Ag was facilely coated onto an electrode as a composite electrode.•Ag coated HCDI showed superior deionization capacity and rate.•Low voltage operation in Ag coated HCDI resulted in good energy efficiency.
AbstractList Capacitive deionization (CDI) using capacitive electrodes is highlighted as an alternative desalination technology because of its advantages of low cost and high energy-efficiency. However, the deionization capacity of CDI is somewhat limited because its capacity relies on the double layer capacitance of a carbon electrode. Thus, improving the deionization capacity of a CDI system is one of the most urgent issues in CDI technology. Herein, Ag coated carbon composite electrode employed hybrid CDI system (Ag coated HCDI) was investigated to enhance the deionization performances. The Ag coated carbon composite electrode was made by coating a small amount of Ag onto a carbon capacitive electrode, exhibiting the characteristics of a battery and a capacitor together. As major results, the CDI deionization capacity (88% more), rate (39% more), and charge efficiency (76%➔92%) was dramatically enhanced due to the Ag coating. The significant improvement in deionization performance is explained by the enhanced specific capacity combining the capacitance in the carbon electrode with the Ag mediated charge transfer reaction. In addition, the Ag coated HCDI (73.3kJmole−1) is superior to membrane assisted CDI (136.7kJmole−1) in terms of energy consumption for deionization due to its low voltage feasible operation. [Display omitted] •Ag was facilely coated onto an electrode as a composite electrode.•Ag coated HCDI showed superior deionization capacity and rate.•Low voltage operation in Ag coated HCDI resulted in good energy efficiency.
Author Lee, Jaehan
Yoon, Hongsik
Kim, Seonghwan
Yoon, Jeyong
Author_xml – sequence: 1
  givenname: Hongsik
  surname: Yoon
  fullname: Yoon, Hongsik
  organization: School of Chemical and Biological Engineering, College of Engineering, Seoul National University (SNU), Gwanak-gu, Daehak-dong, Seoul 151-742, Republic of Korea
– sequence: 2
  givenname: Jaehan
  surname: Lee
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  givenname: Seonghwan
  orcidid: 0000-0002-6061-1802
  surname: Kim
  fullname: Kim, Seonghwan
  organization: School of Chemical and Biological Engineering, College of Engineering, Seoul National University (SNU), Gwanak-gu, Daehak-dong, Seoul 151-742, Republic of Korea
– sequence: 4
  givenname: Jeyong
  surname: Yoon
  fullname: Yoon, Jeyong
  email: jeyong@snu.ac.kr
  organization: School of Chemical and Biological Engineering, College of Engineering, Seoul National University (SNU), Gwanak-gu, Daehak-dong, Seoul 151-742, Republic of Korea
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Keywords Capacitive deionization
Silver
Hybrid capacitive deionization
Desalination
Composite electrode
Language English
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  ident: 10.1016/j.desal.2017.08.010_bb0050
  article-title: Carbon nanotube/graphene composite for enhanced capacitive deionization performance
  publication-title: Carbon
  doi: 10.1016/j.carbon.2013.03.040
  contributor:
    fullname: Wimalasiri
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Snippet Capacitive deionization (CDI) using capacitive electrodes is highlighted as an alternative desalination technology because of its advantages of low cost and...
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SubjectTerms Capacitive deionization
Composite electrode
Desalination
Hybrid capacitive deionization
Silver
Title Hybrid capacitive deionization with Ag coated carbon composite electrode
URI https://dx.doi.org/10.1016/j.desal.2017.08.010
Volume 422
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