Fabrication of InVO4/SnWO4 heterostructured photocatalyst for efficient photocatalytic degradation of tetracycline under visible light

• Published in: Environmental research Vol. 220; p. 115191
• Main Authors: Sreeram, N., Aruna, V., Koutavarapu, Ravindranadh, Lee, Dong-Yeon, Rao, M.C., Shim, Jaesool
• Format: Journal Article
• Language: English
• Published: Elsevier Inc 01-03-2023
• Subjects: Heterostructure; InVO4; Photocatalysis; SnWO4; Tetracycline; Visible light; Heterostructure; Visible light; SnWO4; Photocatalysis; InVO4; Tetracycline
• ISSN: 0013-9351; 1096-0953
• DOI: 10.1016/j.envres.2022.115191

In the present study, novel InVO4/SnWO4 nanocomposites with different concentrations of SnWO4 were successfully prepared using a facile hydrothermal technique and investigated employing a wide range of analytical methods for efficient photocatalytic degradation of tetracycline (TC). X-ray diffraction analysis showed the presence of the orthorhombic phases of both InVO4 and SnWO4 in the composite catalyst. Dispersion of SnWO4 nanoplates over the InVO4 nanosheets enhanced the synergistic interactions, improving the separation of charge carriers and their transfer. Furthermore, the formation of heterostructure expanded the absorption range and promoted visible light harvesting. The TC degradation efficiency of InVO4/SnWO4 nanocomposite (5 mg loading of SnWO4) reached 97.13% in 80 min under visible light, with the kinetic rate constants 5.51 and 7.63 times greater than those of pure InVO4 and SnWO4, respectively. Additionally, the scavenger results proved that hydroxyl radicals and holes played a significant role in the photodegradation of TC. Furthermore, the electrochemical impedance spectroscopy (EIS) and transient photocurrent response analysis showed enhanced e–/h+ partition efficiency. Thus, the formation of heterostructure with strong synergistic interactions can effectively transfer the excited charge carriers and shorten the reunion rate. Accordingly, the InVO4/SnWO4 nanocomposites exhibited remarkable photocatalytic performance due to the increased number of charge carriers on the surface.
•InVO4/SnWO4 nanocomposites were prepared through hydrothermal method.•Formation of heterostructure has been explored by different spectroscopic techniques.•Loading of SnWO4 nanoplates over InVO4 nanosheets reduces the reunion of e−/h+ pairs.•The IVSW-5.0 photocatalyst exhibited 97.13% degradation of TC in 80 min.•Hydroxyl radicals and holes exhibited a dominating role.