Mechanism of Methyl Methacrylate Polymerization Initiated by Benzoyl Peroxide and Ferrocene in the Presence of Oxygen

Mechanism of Methyl Methacrylate Polymerization Initiated by Benzoyl Peroxide and Ferrocene in the Presence of Oxygen

The role of the ferrocenium radical cation and Cp2Fe+–O radical in the initiation of methyl methacrylate polymerization in the absence and presence of oxygen was demonstrated.

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Bibliographic Details
Published in:Mendeleev communications Vol. 23; no. 1; pp. 53 - 55
Main Authors: Murinov, Yury I., Grabovskiy, Stanislav A., Islamova, Regina M., Kuramshina, Al’bina R., Kabal’nova, Natalia N.
Format: Journal Article
Language:English
Published: Elsevier B.V 01-01-2013
Subjects:
Benzoyl peroxide
Cationic polymerization
Ferrocenes
Polymerization
Polymethyl methacrylates
Radicals
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Description
Summary:The role of the ferrocenium radical cation and Cp2Fe+–O radical in the initiation of methyl methacrylate polymerization in the absence and presence of oxygen was demonstrated.
Bibliography:ObjectType-Article-2
SourceType-Scholarly Journals-1
ObjectType-Feature-1
content type line 23
ISSN:0959-9436
DOI:10.1016/j.mencom.2013.01.020