Silver production from spent zinc-silver oxide batteries via leaching-cementation technique

Silver recovery from a spent submarine battery was investigated. The effect of different parameters including nitric acid concentration, temperature, solid to liquid ratio (w/v%) and time was studied and results revealed that recovery increased by increasing acid concentration, temperature (up to 55...

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Published in:	Separation science and technology Vol. 56; no. 11; pp. 1956 - 1964
Main Authors:	Javanshir, Sepideh, Saei Qashoqchi, Safar, Heidari Mofrad, Zahra
Format:	Journal Article
Language:	English
Published:	Abingdon Taylor & Francis 24-07-2021 Taylor & Francis Ltd
Subjects:	Batteries Cementation Copper copper powder Leaching Nitric acid Nitric acids Recovery Silver silver leaching Silver oxides Temperature Zinc Zinc-silver oxide battery
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Abstract	Silver recovery from a spent submarine battery was investigated. The effect of different parameters including nitric acid concentration, temperature, solid to liquid ratio (w/v%) and time was studied and results revealed that recovery increased by increasing acid concentration, temperature (up to 55°C) and solid to liquid ratio (up to 40 g/L). Recovery of silver could reach 99.99% under optimum conditions and the activation energy was found to be 22.84 KJ/mol. Moreover, the effect of Cu/Ag ratio (w %), time, pH and temperature on the precipitation of silver from PLS was studied by surface response methodology (RSM).
AbstractList	Silver recovery from a spent submarine battery was investigated. The effect of different parameters including nitric acid concentration, temperature, solid to liquid ratio (w/v%) and time was studied and results revealed that recovery increased by increasing acid concentration, temperature (up to 55°C) and solid to liquid ratio (up to 40 g/L). Recovery of silver could reach 99.99% under optimum conditions and the activation energy was found to be 22.84 KJ/mol. Moreover, the effect of Cu/Ag ratio (w %), time, pH and temperature on the precipitation of silver from PLS was studied by surface response methodology (RSM). Silver recovery from a spent submarine battery was investigated. The effect of different parameters including nitric acid concentration, temperature, solid to liquid ratio (w/v%) and time was studied and results revealed that recovery increased by increasing acid concentration, temperature (up to 55°C) and solid to liquid ratio (up to 40 g/L). Recovery of silver could reach 99.99% under optimum conditions and the activation energy was found to be 22.84 KJ/mol. Moreover, the effect of Cu/Ag ratio (w %), time, pH and temperature on the precipitation of silver from PLS was studied by surface response methodology (RSM).
Author	Saei Qashoqchi, Safar Javanshir, Sepideh Heidari Mofrad, Zahra
Author_xml	– sequence: 1 givenname: Sepideh surname: Javanshir fullname: Javanshir, Sepideh email: sjavanshir@birjand.ac.ir organization: University of Birjand – sequence: 2 givenname: Safar surname: Saei Qashoqchi fullname: Saei Qashoqchi, Safar organization: University of Birjand – sequence: 3 givenname: Zahra surname: Heidari Mofrad fullname: Heidari Mofrad, Zahra organization: University of Birjand
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SubjectTerms	Batteries Cementation Copper copper powder Leaching Nitric acid Nitric acids Recovery Silver silver leaching Silver oxides Temperature Zinc Zinc-silver oxide battery
Title	Silver production from spent zinc-silver oxide batteries via leaching-cementation technique
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