Solid-state ion sensors with a liquid junction-free polymer membrane-based reference electrode for blood analysis
A set of ion-selective membranes for the measurement of clinically relevant electrolytes, i.e., K +, Na +, Ca 2+, H + and Cl −, and a solvent-processible polyurethane (PU)-based reference membrane were cast on metal electrodes patterned on small ceramic plates, and on silicon-based sensors. Since th...
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| Published in: | Sensors and actuators. B, Chemical Vol. 64; no. 1; pp. 8 - 14 |
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| Main Authors: | , , , , , , |
| Format: | Journal Article |
| Language: | English |
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Elsevier B.V
10-06-2000
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| Abstract | A set of ion-selective membranes for the measurement of clinically relevant electrolytes, i.e., K
+, Na
+, Ca
2+, H
+ and Cl
−, and a solvent-processible polyurethane (PU)-based reference membrane were cast on metal electrodes patterned on small ceramic plates, and on silicon-based sensors. Since the liquid junction-free PU membrane-based reference electrode provides a constant potentiometric signal for an extended period of time, accurate determination of blood electrolytes could be made without using a separate reference flow. The PU membrane-based reference electrodes not only improve the mass producibility of miniaturized solid-state ion sensors but also simplify the configuration of flow cell cartridges without compromising their analytical performance. |
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| AbstractList | A set of ion-selective membranes for the measurement of clinically relevant electrolytes, i.e., K super(+), Na super(+), Ca super(2+), H super(+) and Cl super(-), and a solvent-processible polyurethane (PU)-based reference membrane were cast on metal electrodes patterned on small ceramic plates, and on silicon-based sensors. Since the liquid junction-free PU membrane-based reference electrode provides a constant potentiometric signal for an extended period of time, accurate determination of blood electrolytes could be made without using a separate reference flow. The PU membrane-based reference electrodes not only improve the mass producibility of miniaturized solid-state ion sensors but also simplify the configuration of flow cell cartridges without compromising their analytical performance. A set of ion-selective membranes for the measurement of clinically relevant electrolytes, i.e., K +, Na +, Ca 2+, H + and Cl −, and a solvent-processible polyurethane (PU)-based reference membrane were cast on metal electrodes patterned on small ceramic plates, and on silicon-based sensors. Since the liquid junction-free PU membrane-based reference electrode provides a constant potentiometric signal for an extended period of time, accurate determination of blood electrolytes could be made without using a separate reference flow. The PU membrane-based reference electrodes not only improve the mass producibility of miniaturized solid-state ion sensors but also simplify the configuration of flow cell cartridges without compromising their analytical performance. |
| Author | Cha, Geun Sig Lee, Sung Dong Strong, Timothy D Yoon, Hyo Jung Brown, Richard B Shin, Jae Ho Nam, Hakhyun |
| Author_xml | – sequence: 1 givenname: Hyo Jung surname: Yoon fullname: Yoon, Hyo Jung organization: Chemical Sensor Research Group, Department of Chemistry, Kwangwoon University, 447-1 Wolgye-dong, Nowon-ku, Seoul 139-701, South Korea – sequence: 2 givenname: Jae Ho surname: Shin fullname: Shin, Jae Ho organization: Chemical Sensor Research Group, Department of Chemistry, Kwangwoon University, 447-1 Wolgye-dong, Nowon-ku, Seoul 139-701, South Korea – sequence: 3 givenname: Sung Dong surname: Lee fullname: Lee, Sung Dong organization: Chemical Sensor Research Group, Department of Chemistry, Kwangwoon University, 447-1 Wolgye-dong, Nowon-ku, Seoul 139-701, South Korea – sequence: 4 givenname: Hakhyun surname: Nam fullname: Nam, Hakhyun email: namh@daisy.kwangwoon.ac.kr organization: Chemical Sensor Research Group, Department of Chemistry, Kwangwoon University, 447-1 Wolgye-dong, Nowon-ku, Seoul 139-701, South Korea – sequence: 5 givenname: Geun Sig surname: Cha fullname: Cha, Geun Sig organization: Chemical Sensor Research Group, Department of Chemistry, Kwangwoon University, 447-1 Wolgye-dong, Nowon-ku, Seoul 139-701, South Korea – sequence: 6 givenname: Timothy D surname: Strong fullname: Strong, Timothy D organization: Center for Integrated MicroSystems, Department of Electrical Engineering and Computer Science 2403 EECS, University of Michigan, Ann Arbor, MI 48109-2122, USA – sequence: 7 givenname: Richard B surname: Brown fullname: Brown, Richard B email: brown@umich.edu organization: Center for Integrated MicroSystems, Department of Electrical Engineering and Computer Science 2403 EECS, University of Michigan, Ann Arbor, MI 48109-2122, USA |
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| Cites_doi | 10.1021/ac970690y 10.1021/ac00286a048 10.1016/S0003-2670(00)82761-0 10.1016/S0003-2670(98)00174-3 10.1021/ac980265k 10.1039/an9881301029 10.1002/(SICI)1521-4109(199904)11:4<260::AID-ELAN260>3.0.CO;2-# 10.1002/(SICI)1521-4109(199907)11:10/11<788::AID-ELAN788>3.0.CO;2-4 10.1016/S0003-2670(00)84189-6 10.1021/ac9605455 |
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| Keywords | Polyurethane-based ion-selective membranes All-solid-state ion sensors Ion-selective electrode Miniaturized ion sensors Liquid junction-free reference electrode |
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| References | Yun, Hong, Oh, Cha, Nam, Lee, Jin (BIB6) 1997; 69 Burtis, Ashwood (BIB1) 1994 Sudholter, van der Wal, Skowronska-Ptasinska, van den Berg, Bergveld, Reinhoudt (BIB11) 1990; 230 I.R. Lauks, Reference electrode, method of making and method of using same, USA patent No. 4933048, 1988. Lee, Hong, Lee, Shin, Nam, Cha (BIB3) 1998; 70 Yoon, Shin, Paeng, Nam, Cha, Paeng (BIB4) 1998; 367 Lee, Lee, Cui, Lee, Shin, Cha, Nam (BIB5) 1999; 11 Fogt, Untereker, Norenberg, Meyerhoff (BIB9) 1985; 57 van den Vlekkert, Francis, Grisel, de Rooij (BIB10) 1988; 113 Mathison, Bakker (BIB8) 1998; 70 Bakker (BIB7) 1999; 11 Ammann, Pretsch, Simon, Lindner, Bezegh, Pungor (BIB13) 1985; 171 Meruva, Malinowska, Hower, Brown, Meyerhoff (BIB12) 1995 van den Vlekkert (10.1016/S0925-4005(99)00476-1_BIB10) 1988; 113 Yun (10.1016/S0925-4005(99)00476-1_BIB6) 1997; 69 Burtis (10.1016/S0925-4005(99)00476-1_BIB1) 1994 Lee (10.1016/S0925-4005(99)00476-1_BIB3) 1998; 70 Bakker (10.1016/S0925-4005(99)00476-1_BIB7) 1999; 11 Ammann (10.1016/S0925-4005(99)00476-1_BIB13) 1985; 171 10.1016/S0925-4005(99)00476-1_BIB2 Lee (10.1016/S0925-4005(99)00476-1_BIB5) 1999; 11 Mathison (10.1016/S0925-4005(99)00476-1_BIB8) 1998; 70 Meruva (10.1016/S0925-4005(99)00476-1_BIB12) 1995 Fogt (10.1016/S0925-4005(99)00476-1_BIB9) 1985; 57 Sudholter (10.1016/S0925-4005(99)00476-1_BIB11) 1990; 230 Yoon (10.1016/S0925-4005(99)00476-1_BIB4) 1998; 367 |
| References_xml | – volume: 69 start-page: 868 year: 1997 end-page: 873 ident: BIB6 article-title: Potentiometric properties of ion-selective electrode membranes based on segmented polyether urethane matrices publication-title: Anal. Chem. contributor: fullname: Jin – volume: 57 start-page: 1995 year: 1985 end-page: 1998 ident: BIB9 article-title: Response of ion-selective field-effect transistors to carbon dioxide and organic acids publication-title: Anal. Chem. contributor: fullname: Meyerhoff – volume: 230 start-page: 59 year: 1990 end-page: 65 ident: BIB11 article-title: Modification of ISFETs by covalent anchoring of poly(hydroxyethyl methacrylate) hydrogel. Introduction of a thermodynamically defined semiconductor-sensing membrane interface publication-title: Anal. Chim. 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Chim. Acta doi: 10.1016/S0003-2670(00)84189-6 contributor: fullname: Ammann – year: 1994 ident: 10.1016/S0925-4005(99)00476-1_BIB1 contributor: fullname: Burtis – volume: 69 start-page: 868 year: 1997 ident: 10.1016/S0925-4005(99)00476-1_BIB6 article-title: Potentiometric properties of ion-selective electrode membranes based on segmented polyether urethane matrices publication-title: Anal. Chem. doi: 10.1021/ac9605455 contributor: fullname: Yun – ident: 10.1016/S0925-4005(99)00476-1_BIB2 |
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+, Na
+, Ca
2+, H
+ and Cl
−, and a solvent-processible... A set of ion-selective membranes for the measurement of clinically relevant electrolytes, i.e., K super(+), Na super(+), Ca super(2+), H super(+) and Cl... |
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| SubjectTerms | All-solid-state ion sensors Blood Electrolytes Ion selective electrodes Ion selective membranes Ion-selective electrode Liquid junction-free reference electrode Miniaturized ion sensors Polyurethane-based ion-selective membranes Polyurethanes Solid state devices |
| Title | Solid-state ion sensors with a liquid junction-free polymer membrane-based reference electrode for blood analysis |
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