Models for positive charge fluctuation vs. spin polarization in organic systems; synthesis and cyclic voltammetry of 2D and 1D hyperbranched π -aryl-based amines

• Published in: Synthetic metals Vol. 85; no. 1; pp. 1665 - 1666
• Main Authors: Yano, M., Furuichi, M., Sato, K., Shiomi, D., Ichimura, A., Abe, K., Takui, T., Itoh, K.
• Format: Journal Article Conference Proceeding
• Language: English
• Published: Lausanne Elsevier B.V 15-03-1997; Amsterdam Elsevier Science; New York, NY
• Subjects: Chemistry; electrochemical methods; Electrochemistry; Exact sciences and technology; General and physical chemistry; Kinetics and mechanism of reactions; other conjugated and/or conducting polymers; other conjugated and/or conducting polymers; electrochemical methods; Organic solvent; Oxidation reduction; Electrochemical properties; Tertiary amine; Benzenic compound; Experimental study; Organic compounds
• ISSN: 0379-6779; 1879-3290
• DOI: 10.1016/S0379-6779(97)80388-8

A series of substituted
N,N,N′,N′,N″,N″hexaphenyl-1,3,5-triaminobenzene(TAB) and
N,N,N′,N′tetraphenyl-1,3,5 triaminobenzene(DAB) were synthesized as models for positive charged fluctuation vs. spin polarization in organic systems. CV measurements at low temperature showed that the chemical stability-in-solution of mono and poly-cationic oxidation states of the various HPTABs and TPDABs derivatives depend on their molecular structures and substituents.