Highly precise determination of the heat capacity of liquids by DSC: calibration and measurement

The heat capacities of various liquids were determined with a high precision using differential scanning calorimetry. The calibration and measurement procedures, as implemented on a Setaram Micro DSC II calorimeter based on Calvet’s differential detection of the heat flow rate in the measuring and r...

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Published in:Thermochimica acta Vol. 347; no. 1; pp. 37 - 44
Main Authors: Cerdeiriña, C.A, Mı́guez, J.A, Carballo, E, Tovar, C.A, de la Puente, E, Romanı́, Luis
Format: Journal Article Conference Proceeding
Language:English
Published: Amsterdam Elsevier B.V 17-04-2000
Elsevier Science
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Abstract The heat capacities of various liquids were determined with a high precision using differential scanning calorimetry. The calibration and measurement procedures, as implemented on a Setaram Micro DSC II calorimeter based on Calvet’s differential detection of the heat flow rate in the measuring and reference vessels are analysed and discussed. An experimental procedure for determining heat capacities based on the scanning method is proposed. Calibration is done with liquids of known heat capacity. The proposed method was checked against various standard liquids. The results of ensuing scanning method are compared with those obtained by using the isothermal step method.
AbstractList The heat capacities of various liquids were determined with a high precision using differential scanning calorimetry. The calibration and measurement procedures, as implemented on a Setaram Micro DSC II calorimeter based on Calvet’s differential detection of the heat flow rate in the measuring and reference vessels are analysed and discussed. An experimental procedure for determining heat capacities based on the scanning method is proposed. Calibration is done with liquids of known heat capacity. The proposed method was checked against various standard liquids. The results of ensuing scanning method are compared with those obtained by using the isothermal step method.
Author de la Puente, E
Romanı́, Luis
Cerdeiriña, C.A
Carballo, E
Tovar, C.A
Mı́guez, J.A
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  fullname: Mı́guez, J.A
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  givenname: Luis
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  fullname: Romanı́, Luis
  email: fisapor@setei.uvigo.es
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Issue 1
Keywords Measurement
Heat capacity
Calibration
Organic liquids
DSC
Thermal properties
Differential scanning calorimetry
Liquid
Accuracy
Excess parameter
Thermal analysis
Organic compounds
Language English
License CC BY 4.0
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Snippet The heat capacities of various liquids were determined with a high precision using differential scanning calorimetry. The calibration and measurement...
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SubjectTerms Analytical chemistry
Calibration
Chemical and thermal methods
Chemistry
DSC
Exact sciences and technology
Heat capacity
Measurement
Organic liquids
Title Highly precise determination of the heat capacity of liquids by DSC: calibration and measurement
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