Ionic liquid crystals: synthesis and mesomorphic properties of dimeric 2,4,6-triarylpyrylium tetrafluoroborates

The synthesis of some dimeric pyrylium salts is described. The link between the two cationic parts of the molecule can be flexible or rigid. Surprisingly, the starting dimeric chalcones with a rigid link exhibit monotropic columnar hexagonal phases. Results concerning the spectroscopic and mesomorph...

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Bibliographic Details
Published in:Liquid crystals Vol. 27; no. 5; pp. 671 - 676
Main Authors: Veber, M., Berruyer, G.
Format: Journal Article
Language:English
Published: Taylor & Francis Group 01-05-2000
Online Access:Get full text
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Summary:The synthesis of some dimeric pyrylium salts is described. The link between the two cationic parts of the molecule can be flexible or rigid. Surprisingly, the starting dimeric chalcones with a rigid link exhibit monotropic columnar hexagonal phases. Results concerning the spectroscopic and mesomorphic properties of the pyrylium salts and the chalcones are given.
ISSN:0267-8292
1366-5855
DOI:10.1080/026782900202534