Pyroelectric properties and electrical conductivity in samarium doped BiFeO3 ceramics
► Fabrication of Sm-doped BiFeO3 (BFO) ceramics using a modified solid-state reaction method was reported. ► The structural, electrical and pyroelectrical properties of the Sm-doped BFO were characterized. ► The effects of the Sm-dopant on the pyroelectric as well as electrical properties of BFO wer...
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Published in: | Journal of alloys and compounds Vol. 527; pp. 157 - 162 |
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Abstract | ► Fabrication of Sm-doped BiFeO3 (BFO) ceramics using a modified solid-state reaction method was reported. ► The structural, electrical and pyroelectrical properties of the Sm-doped BFO were characterized. ► The effects of the Sm-dopant on the pyroelectric as well as electrical properties of BFO were revealed. ► The magnetic Néel temperature decreased with increasing Sm3+ doping level.
Samarium (Sm3+) doped BiFeO3 (BFO) ceramics were prepared by a modified solid-state-reaction method which adopted a rapid heating as well as cooling during the sintering process. The pyroelectric coefficient increased from 93 to 137μC/m2K as the Sm3+ doping level increased from 1mol% to 8mol%. Temperature dependence of the pyroelectric coefficient showed an abrupt decrease above 80°C in all samples, which was associated with the increase of electrical conductivity with temperature. This electrical conduction was attributed to oxygen vacancy existing in the samples. An activation energy of ∼0.7eV for the conduction process was found to be irrespective of the Sm3+ doping level. On the other hand, the magnetic Néel temperature (TN) decreased with increasing Sm3+ doping level. On the basis of our results, the effects of Sm doping level on the pyroelectric and electrical properties of the BFO were revealed. |
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AbstractList | Samarium (Sm3+) doped BiFeO3 (BFO) ceramics were prepared by a modified solid-state-reaction method which adopted a rapid heating as well as cooling during the sintering process. The pyroelectric coefficient increased from 93 to 137 I14C/m2 K as the Sm3+ doping level increased from 1 mol% to 8 mol%. Temperature dependence of the pyroelectric coefficient showed an abrupt decrease above 80 [deg]C in all samples, which was associated with the increase of electrical conductivity with temperature. This electrical conduction was attributed to oxygen vacancy existing in the samples. An activation energy of a140.7 eV for the conduction process was found to be irrespective of the Sm3+ doping level. On the other hand, the magnetic Neel temperature (TN) decreased with increasing Sm3+ doping level. On the basis of our results, the effects of Sm doping level on the pyroelectric and electrical properties of the BFO were revealed. ► Fabrication of Sm-doped BiFeO3 (BFO) ceramics using a modified solid-state reaction method was reported. ► The structural, electrical and pyroelectrical properties of the Sm-doped BFO were characterized. ► The effects of the Sm-dopant on the pyroelectric as well as electrical properties of BFO were revealed. ► The magnetic Néel temperature decreased with increasing Sm3+ doping level. Samarium (Sm3+) doped BiFeO3 (BFO) ceramics were prepared by a modified solid-state-reaction method which adopted a rapid heating as well as cooling during the sintering process. The pyroelectric coefficient increased from 93 to 137μC/m2K as the Sm3+ doping level increased from 1mol% to 8mol%. Temperature dependence of the pyroelectric coefficient showed an abrupt decrease above 80°C in all samples, which was associated with the increase of electrical conductivity with temperature. This electrical conduction was attributed to oxygen vacancy existing in the samples. An activation energy of ∼0.7eV for the conduction process was found to be irrespective of the Sm3+ doping level. On the other hand, the magnetic Néel temperature (TN) decreased with increasing Sm3+ doping level. On the basis of our results, the effects of Sm doping level on the pyroelectric and electrical properties of the BFO were revealed. |
Author | Mak, C.L. Yao, Y.B. Liu, W.C. |
Author_xml | – sequence: 1 givenname: Y.B. surname: Yao fullname: Yao, Y.B. organization: Department of Applied Physics, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong SAR, China – sequence: 2 givenname: W.C. surname: Liu fullname: Liu, W.C. organization: Department of Applied Physics, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong SAR, China – sequence: 3 givenname: C.L. surname: Mak fullname: Mak, C.L. email: apaclmak@polyu.edu.hk organization: Department of Applied Physics, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong SAR, China |
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Keywords | Pyroelectric BiFeO3 Sm3+ doping Electrical conductivity Vacancies Cooling Doping Bismuth Iron Oxides Mixed Pyroelectricity Electrical model Samarium additions Sintering Solid state reaction BiFe0 Neel temperature Sm Permittivity Activation energy |
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Snippet | ► Fabrication of Sm-doped BiFeO3 (BFO) ceramics using a modified solid-state reaction method was reported. ► The structural, electrical and pyroelectrical... Samarium (Sm3+) doped BiFeO3 (BFO) ceramics were prepared by a modified solid-state-reaction method which adopted a rapid heating as well as cooling during the... |
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SubjectTerms | BiFeO3 Ceramics Coefficients Condensed matter: electronic structure, electrical, magnetic, and optical properties Dielectric properties of solids and liquids Dielectrics, piezoelectrics, and ferroelectrics and their properties Doping Electrical conductivity Electrical properties Electrical resistivity Exact sciences and technology Permittivity (dielectric function) Physics Pyroelectric Pyroelectric and electrocaloric effects Resistivity Samarium Sm3+ doping |
Title | Pyroelectric properties and electrical conductivity in samarium doped BiFeO3 ceramics |
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