Pyroelectric properties and electrical conductivity in samarium doped BiFeO3 ceramics

► Fabrication of Sm-doped BiFeO3 (BFO) ceramics using a modified solid-state reaction method was reported. ► The structural, electrical and pyroelectrical properties of the Sm-doped BFO were characterized. ► The effects of the Sm-dopant on the pyroelectric as well as electrical properties of BFO wer...

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Published in:Journal of alloys and compounds Vol. 527; pp. 157 - 162
Main Authors: Yao, Y.B., Liu, W.C., Mak, C.L.
Format: Journal Article
Language:English
Published: Kidlington Elsevier B.V 25-06-2012
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Abstract ► Fabrication of Sm-doped BiFeO3 (BFO) ceramics using a modified solid-state reaction method was reported. ► The structural, electrical and pyroelectrical properties of the Sm-doped BFO were characterized. ► The effects of the Sm-dopant on the pyroelectric as well as electrical properties of BFO were revealed. ► The magnetic Néel temperature decreased with increasing Sm3+ doping level. Samarium (Sm3+) doped BiFeO3 (BFO) ceramics were prepared by a modified solid-state-reaction method which adopted a rapid heating as well as cooling during the sintering process. The pyroelectric coefficient increased from 93 to 137μC/m2K as the Sm3+ doping level increased from 1mol% to 8mol%. Temperature dependence of the pyroelectric coefficient showed an abrupt decrease above 80°C in all samples, which was associated with the increase of electrical conductivity with temperature. This electrical conduction was attributed to oxygen vacancy existing in the samples. An activation energy of ∼0.7eV for the conduction process was found to be irrespective of the Sm3+ doping level. On the other hand, the magnetic Néel temperature (TN) decreased with increasing Sm3+ doping level. On the basis of our results, the effects of Sm doping level on the pyroelectric and electrical properties of the BFO were revealed.
AbstractList Samarium (Sm3+) doped BiFeO3 (BFO) ceramics were prepared by a modified solid-state-reaction method which adopted a rapid heating as well as cooling during the sintering process. The pyroelectric coefficient increased from 93 to 137 I14C/m2 K as the Sm3+ doping level increased from 1 mol% to 8 mol%. Temperature dependence of the pyroelectric coefficient showed an abrupt decrease above 80 [deg]C in all samples, which was associated with the increase of electrical conductivity with temperature. This electrical conduction was attributed to oxygen vacancy existing in the samples. An activation energy of a140.7 eV for the conduction process was found to be irrespective of the Sm3+ doping level. On the other hand, the magnetic Neel temperature (TN) decreased with increasing Sm3+ doping level. On the basis of our results, the effects of Sm doping level on the pyroelectric and electrical properties of the BFO were revealed.
► Fabrication of Sm-doped BiFeO3 (BFO) ceramics using a modified solid-state reaction method was reported. ► The structural, electrical and pyroelectrical properties of the Sm-doped BFO were characterized. ► The effects of the Sm-dopant on the pyroelectric as well as electrical properties of BFO were revealed. ► The magnetic Néel temperature decreased with increasing Sm3+ doping level. Samarium (Sm3+) doped BiFeO3 (BFO) ceramics were prepared by a modified solid-state-reaction method which adopted a rapid heating as well as cooling during the sintering process. The pyroelectric coefficient increased from 93 to 137μC/m2K as the Sm3+ doping level increased from 1mol% to 8mol%. Temperature dependence of the pyroelectric coefficient showed an abrupt decrease above 80°C in all samples, which was associated with the increase of electrical conductivity with temperature. This electrical conduction was attributed to oxygen vacancy existing in the samples. An activation energy of ∼0.7eV for the conduction process was found to be irrespective of the Sm3+ doping level. On the other hand, the magnetic Néel temperature (TN) decreased with increasing Sm3+ doping level. On the basis of our results, the effects of Sm doping level on the pyroelectric and electrical properties of the BFO were revealed.
Author Mak, C.L.
Yao, Y.B.
Liu, W.C.
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  fullname: Mak, C.L.
  email: apaclmak@polyu.edu.hk
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Keywords Pyroelectric
BiFeO3
Sm3+ doping
Electrical conductivity
Vacancies
Cooling
Doping
Bismuth Iron Oxides Mixed
Pyroelectricity
Electrical model
Samarium additions
Sintering
Solid state reaction
BiFe0
Neel temperature
Sm
Permittivity
Activation energy
Language English
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Elsevier
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Snippet ► Fabrication of Sm-doped BiFeO3 (BFO) ceramics using a modified solid-state reaction method was reported. ► The structural, electrical and pyroelectrical...
Samarium (Sm3+) doped BiFeO3 (BFO) ceramics were prepared by a modified solid-state-reaction method which adopted a rapid heating as well as cooling during the...
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SubjectTerms BiFeO3
Ceramics
Coefficients
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Dielectric properties of solids and liquids
Dielectrics, piezoelectrics, and ferroelectrics and their properties
Doping
Electrical conductivity
Electrical properties
Electrical resistivity
Exact sciences and technology
Permittivity (dielectric function)
Physics
Pyroelectric
Pyroelectric and electrocaloric effects
Resistivity
Samarium
Sm3+ doping
Title Pyroelectric properties and electrical conductivity in samarium doped BiFeO3 ceramics
URI https://dx.doi.org/10.1016/j.jallcom.2012.02.182
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