Effect of silicate-based films on the corrosion behavior of the API 5L X80 pipeline steel

Effect of silicate-based films on the corrosion behavior of the API 5L X80 pipeline steel

[Display omitted] •Silicate-based films were obtained on API 5L X80 pipeline steel.•Silicon was present mainly as SiO2 on the anodic treatment film.•Corrosion resistance depends on the silica concentration in the fil.•Anodic treatment provided superior corrosion resistance. The aim of this work was...

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Published in:Corrosion science Vol. 139; pp. 21 - 34
Main Authors: de Oliveira, Leandro Antonio, Correa, Olandir Vercino, dos Santos, Demetrio Jackson, Páez, Alejandro Andrés Zúñiga, de Oliveira, Mara Cristina Lopes, Antunes, Renato Altobelli
Format: Journal Article
Language:English
Published: Amsterdam Elsevier Ltd 15-07-2018
Elsevier BV
Subjects:
Adhesion tests
Adhesive strength
Anodic protection
API 5L X80
Bicarbonates
Chemical composition
Corrosion
Corrosion effects
Corrosion mechanisms
Corrosion prevention
Corrosion resistance
Electrochemical impedance spectroscopy
Electrode polarization
High strength low alloy steels
Morphology
Organic chemistry
Pipeline steel
Protective coatings
Pull off tests
Scanning electron microscopy
Sodium silicate films
Sodium silicates
Spectroscopic analysis
Spectrum analysis
Steel
Submerging
XPS
API 5L X80
XPS
Corrosion
Pipeline steel
Sodium silicate films
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Abstract [Display omitted] •Silicate-based films were obtained on API 5L X80 pipeline steel.•Silicon was present mainly as SiO2 on the anodic treatment film.•Corrosion resistance depends on the silica concentration in the fil.•Anodic treatment provided superior corrosion resistance. The aim of this work was to investigate the effect of silicate-based films on the corrosion resistance of the API 5L X80 steel in carbonate-bicarbonate solution at room temperature. The films were electrochemically obtained by anodic and cathodic treatments and by immersion in 1.0 M sodium metasilicate solution. The corrosion behavior was evaluated using electrochemical impedance spectroscopy and potentiodynamic polarization. Film morphology was examined by scanning electron microscopy. Adhesion strength was measured by pull-off tests. The chemical composition was evaluated by X-ray photoelectron spectroscopy. The anodic film yielded the best corrosion resistance (protection efficiency 83%). The protection mechanism is discussed.
AbstractList The aim of this work was to investigate the effect of silicate-based films on the corrosion resistance of the API 5L X80 steel in carbonate-bicarbonate solution at room temperature. The films were electrochemically obtained by anodic and cathodic treatments and by immersion in 1.0 M sodium metasilicate solution. The corrosion behavior was evaluated using electrochemical impedance spectroscopy and potentiodynamic polarization. Film morphology was examined by scanning electron microscopy. Adhesion strength was measured by pull-off tests. The chemical composition was evaluated by X-ray photoelectron spectroscopy. The anodic film yielded the best corrosion resistance (protection efficiency 83%). The protection mechanism is discussed.
[Display omitted] •Silicate-based films were obtained on API 5L X80 pipeline steel.•Silicon was present mainly as SiO2 on the anodic treatment film.•Corrosion resistance depends on the silica concentration in the fil.•Anodic treatment provided superior corrosion resistance. The aim of this work was to investigate the effect of silicate-based films on the corrosion resistance of the API 5L X80 steel in carbonate-bicarbonate solution at room temperature. The films were electrochemically obtained by anodic and cathodic treatments and by immersion in 1.0 M sodium metasilicate solution. The corrosion behavior was evaluated using electrochemical impedance spectroscopy and potentiodynamic polarization. Film morphology was examined by scanning electron microscopy. Adhesion strength was measured by pull-off tests. The chemical composition was evaluated by X-ray photoelectron spectroscopy. The anodic film yielded the best corrosion resistance (protection efficiency 83%). The protection mechanism is discussed.
Author de Oliveira, Mara Cristina Lopes
Páez, Alejandro Andrés Zúñiga
dos Santos, Demetrio Jackson
de Oliveira, Leandro Antonio
Antunes, Renato Altobelli
Correa, Olandir Vercino
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  givenname: Olandir Vercino
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  givenname: Demetrio Jackson
  surname: dos Santos
  fullname: dos Santos, Demetrio Jackson
  organization: Universidade Federal do ABC (UFABC), Centro de Engenharia, Modelagem e Ciências Sociais Aplicadas (CECS), 09210-580, Santo André, SP, Brazil
– sequence: 4
  givenname: Alejandro Andrés Zúñiga
  surname: Páez
  fullname: Páez, Alejandro Andrés Zúñiga
  organization: Universidade Federal do ABC (UFABC), Centro de Engenharia, Modelagem e Ciências Sociais Aplicadas (CECS), 09210-580, Santo André, SP, Brazil
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  givenname: Mara Cristina Lopes
  surname: de Oliveira
  fullname: de Oliveira, Mara Cristina Lopes
  organization: Universidade Federal do ABC (UFABC), Centro de Engenharia, Modelagem e Ciências Sociais Aplicadas (CECS), 09210-580, Santo André, SP, Brazil
– sequence: 6
  givenname: Renato Altobelli
  surname: Antunes
  fullname: Antunes, Renato Altobelli
  email: renato.antunes@ufabc.edu.br
  organization: Universidade Federal do ABC (UFABC), Centro de Engenharia, Modelagem e Ciências Sociais Aplicadas (CECS), 09210-580, Santo André, SP, Brazil
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Keywords API 5L X80
XPS
Corrosion
Pipeline steel
Sodium silicate films
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Snippet [Display omitted] •Silicate-based films were obtained on API 5L X80 pipeline steel.•Silicon was present mainly as SiO2 on the anodic treatment film.•Corrosion...
The aim of this work was to investigate the effect of silicate-based films on the corrosion resistance of the API 5L X80 steel in carbonate-bicarbonate...
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SubjectTerms Adhesion tests
Adhesive strength
Anodic protection
API 5L X80
Bicarbonates
Chemical composition
Corrosion
Corrosion effects
Corrosion mechanisms
Corrosion prevention
Corrosion resistance
Electrochemical impedance spectroscopy
Electrode polarization
High strength low alloy steels
Morphology
Organic chemistry
Pipeline steel
Protective coatings
Pull off tests
Scanning electron microscopy
Sodium silicate films
Sodium silicates
Spectroscopic analysis
Spectrum analysis
Steel
Submerging
XPS
Title Effect of silicate-based films on the corrosion behavior of the API 5L X80 pipeline steel
URI https://dx.doi.org/10.1016/j.corsci.2018.04.035
https://www.proquest.com/docview/2103109536
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