Transparent conducting films made of different carbon nanotubes, processed carbon nanotubes, and graphene nanoribbons

• Published in: Chemical engineering science Vol. 138; pp. 566 - 574
• Main Authors: Ansón-Casaos, Alejandro, Mis-Fernández, Ricardo, López-Alled, Carlos M., Almendro-López, Eduardo, Hernández-Ferrer, Javier, González-Domínguez, José Miguel, Martínez, M. Teresa
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 22-12-2015
• Subjects: Carbon nanostructures; Ink; Sheet resistivity; Spray coating; Transparency; Transparency; Carbon nanostructures; Sheet resistivity; Spray coating; Ink
• ISSN: 0009-2509; 1873-4405
• DOI: 10.1016/j.ces.2015.09.002

Transparent conducting films (TCFs) are made of different single-walled (SW) or multi-walled (MW) carbon nanotubes (CNTs), some of them previously modified by chemical or physical processes. The TCFs are prepared by spray-coating of CNT surfactant dispersions over glass substrates. Among pristine CNTs, laser-grown SWCNTs lead to the lowest resistivity, even though good results can be achieved with other selected SW or MWCNTs. Ultracentrifugation of the SWCNT dispersions can be utilized for improving the characteristic SWCNT spectroscopic signals. Controlled oxidation, acid treatment, and covalent functionalization with aromatic organic groups can be applied to CNT solid powders without substantially increasing the resulting TCF resistivity. The oxidative transformation of arc-discharge MWCNTs into graphene nanoribbons relatively improves their TCF performance. The positive effects of TCF washing with water or oxidant acids are quantified for various SWCNT types. Red and green inks, enriched in metallic or semiconducting SWCNTs, are obtained by the gel-chromatographic method, all the fractions being useful for the preparation of TCFs. Thus, it is shown that different physical and chemical processes can be performed on CNTs before or after their deposition, demonstrating a great chemical versatility for CNT-TCFs.
•Transparent conducting films are fabricated of eight carbon nanotube materials.•Carbon nanotubes for the films can bear many physicochemical transformations.•Certain nanotube electronic properties can vary without losing film conductivity.•Single-walled carbon nanotubes are sorted by the gel chromatography method.•Graphene nanoribbons are also tested.