Photothermal, photoconductive and nonlinear optical effects induced by nanosecond pulse irradiation in multi-wall carbon nanotubes

• Published in: Materials science & engineering. B, Solid-state materials for advanced technology Vol. 194; pp. 27 - 33
• Main Authors: García-Merino, J.A., Martínez-González, C.L., Miguel, C.R. Torres-San, Trejo-Valdez, M., Martínez-Gutiérrez, H., Torres-Torres, C.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01-04-2015
• Subjects: Aerosols; Carbon nanotubes; Kerr effects; Materials science; Mathematical models; Multi wall carbon nanotubes; Nonlinear optics; Nonlinearity; Optical properties; Photoconductivity; Pyrolysis; Thermal response; Carbon nanotubes; Photoconductivity; Nonlinear optics; Thermal response
• ISSN: 0921-5107; 1873-4944
• DOI: 10.1016/j.mseb.2014.12.022

•Carbon nanotubes were prepared by an aerosol pyrolysis method.•Thermal phenomena were induced by nanosecond irradiation.•Photoconductive and nonlinear optical properties were evaluated.•A monostable multivibrator function in carbon nanotubes was analyzed.
The influence of the optical absorption exhibited by multi-wall carbon nanotubes on their photothermal, photoconductive and nonlinear optical properties was evaluated. The experiments were performed by using a Nd:YAG laser system at 532nm wavelength and 1ns pulse duration. The observations were carried out in thin film samples conformed by carbon nanotubes prepared by an aerosol pyrolysis method; Raman spectroscopy studies confirmed their multi-wall nature. Theoretical and numerical calculations based on the heat equation allow us to predict the temporal response of the induced effects associated to the optical energy transference. A two-wave mixing method was employed to explore the third order nonlinear optical response exhibited by the sample. A dominant thermal process was identified as the main physical mechanism responsible for the optical Kerr effect. Potential applications for developing a monostable multivibrator exhibiting different time-resolved characteristics were analyzed.