Metal-based reactive nanomaterials

• Published in: Progress in energy and combustion science Vol. 35; no. 2; pp. 141 - 167
• Main Author: Dreizin, Edward L.
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier Ltd 01-04-2009; Elsevier
• Subjects: Applied sciences; Combustion. Flame; Composite; Energetic materials; Energy; Energy. Thermal use of fuels; Exact sciences and technology; Materials synthesis; Metal combustion; Miscellaneous; Nanoaluminum; Theoretical studies. Data and constants. Metering; Thermites; Thermites; Metal combustion; Nanoaluminum; Composite; Materials synthesis; Energetic materials; Enthalpy; Ignition; Combustion; Review; High temperature; Metal; Reaction rate; Thermodynamics; Morphology; Oxidation; Ignition delay; Nanostructured materials; Heterogeneous reaction
• ISSN: 0360-1285; 1873-216X
• DOI: 10.1016/j.pecs.2008.09.001

Recent developments in materials processing and characterization resulted in the discovery of a new type of reactive materials containing nanoscaled metal components. The well-known high oxidation energies of metallic fuels can now be released very rapidly because of the very high reactive interface areas in such metal-based reactive nanomaterials. Consequently, these materials are currently being examined for an entire range of applications in energetic formulations inappropriate for conventional, micron-sized metal fuels having relatively low reaction rates. New application areas, such as reactive structural materials, are also being explored. Research remains active in manufacturing and characterization of metal-based reactive nanomaterials including elemental metal nanopowders and various nanocomposite material systems. Because of the nanometer scale of the individual particles, or phase domains, and because of the very high enthalpy of reaction between components of the nanocomposite materials, the final phase compositions, morphology, and thermodynamic properties of the reactive nanocomposite materials may be different from those of their micron-scaled counterparts. Ignition mechanisms in such materials can be governed by heterogeneous reactions that are insignificant for materials with less developed reactive interface areas. New combustion regimes are being observed that are affected by very short ignition delays combined with very high metal combustion temperatures. Current progress in this rapidly growing research area is reviewed and some potential directions for the future research are discussed.