Synthesis of monoclinic CaSnSiO5 ceramics and their microwave dielectric properties

The monoclinic CaSnSiO5 phase could be synthesized with a conventional solid state method. The molar ratio of Ca:Sn:Si=1:1.05:1 was employed to synthesize pure CaSnSiO5 ceramics through non-stoichiometric effect. The CaSnSiO5 ceramics sintered at 1525°C exhibited microwave dielectric properties: a d...

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Published in:	Materials letters Vol. 91; no. 15; pp. 239 - 241
Main Authors:	Wu, S.P., Chen, D.F., Jiang, C., Mei, Y.X., Ma, Q.
Format:	Journal Article
Language:	English
Published:	Elsevier B.V 15-01-2013
Subjects:	CaSnSiO5 ceramics dielectric properties Dielectrics Electroceramics Microstructure Microwave properties temperature Microwave properties Dielectrics Microstructure CaSnSiO5 Electroceramics
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Abstract	The monoclinic CaSnSiO5 phase could be synthesized with a conventional solid state method. The molar ratio of Ca:Sn:Si=1:1.05:1 was employed to synthesize pure CaSnSiO5 ceramics through non-stoichiometric effect. The CaSnSiO5 ceramics sintered at 1525°C exhibited microwave dielectric properties: a dielectric constant (εr) of 9.08, a quality factor (Q×f) of 61,000GHz and a temperature coefficient of resonant frequency (τf) of 35ppm/°C. They are promising millimeter-wave ceramic materials. ► Monoclinic CaSnSiO5 ceramics were synthesized with a solid-state method. ► Pure CaSnSiO5 ceramics were synthesized by non-stoichiometric effect. ► High relative density and normal microstructure resulted in excellent properties.► Microwave properties of CaSnSiO5: εr=9.08, Q×f=61,000GHz and τf=35ppm/°C. ► CaSnSiO5 ceramics are promising millimeter-wave ceramic materials.
AbstractList	The monoclinic CaSnSiO₅ phase could be synthesized with a conventional solid state method. The molar ratio of Ca:Sn:Si=1:1.05:1 was employed to synthesize pure CaSnSiO₅ ceramics through non-stoichiometric effect. The CaSnSiO₅ ceramics sintered at 1525°C exhibited microwave dielectric properties: a dielectric constant (εᵣ) of 9.08, a quality factor (Q×f) of 61,000GHz and a temperature coefficient of resonant frequency (τf) of 35ppm/°C. They are promising millimeter-wave ceramic materials. The monoclinic CaSnSiO5 phase could be synthesized with a conventional solid state method. The molar ratio of Ca:Sn:Si=1:1.05:1 was employed to synthesize pure CaSnSiO5 ceramics through non-stoichiometric effect. The CaSnSiO5 ceramics sintered at 1525°C exhibited microwave dielectric properties: a dielectric constant (εr) of 9.08, a quality factor (Q×f) of 61,000GHz and a temperature coefficient of resonant frequency (τf) of 35ppm/°C. They are promising millimeter-wave ceramic materials. ► Monoclinic CaSnSiO5 ceramics were synthesized with a solid-state method. ► Pure CaSnSiO5 ceramics were synthesized by non-stoichiometric effect. ► High relative density and normal microstructure resulted in excellent properties.► Microwave properties of CaSnSiO5: εr=9.08, Q×f=61,000GHz and τf=35ppm/°C. ► CaSnSiO5 ceramics are promising millimeter-wave ceramic materials.
Author	Mei, Y.X. Chen, D.F. Ma, Q. Wu, S.P. Jiang, C.
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Snippet	The monoclinic CaSnSiO5 phase could be synthesized with a conventional solid state method. The molar ratio of Ca:Sn:Si=1:1.05:1 was employed to synthesize pure... The monoclinic CaSnSiO₅ phase could be synthesized with a conventional solid state method. The molar ratio of Ca:Sn:Si=1:1.05:1 was employed to synthesize pure...
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Title	Synthesis of monoclinic CaSnSiO5 ceramics and their microwave dielectric properties
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