Novel titanium(IV) diolate complexes with additional O‐donor as precatalyst for the synthesis of ultrahigh molecular weight polyethylene with reduced entanglement density: Influence of polymerization conditions and its implications on mechanical properties

New alkoxo‐titanium(IV) complexes with diolate ligand containing additional donor oxygen atom have been synthesized from readily available and scalable precursors. The structure of complex 4 was established by X‐ray diffraction. Titanium atom adopts a distorted tetrahedral geometry formed by six oxy...

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Bibliographic Details
Published in:	Applied organometallic chemistry Vol. 35; no. 7
Main Authors:	Tuskaev, Vladislav A., Gagieva, Svetlana Ch, Kurmaev, Dmitrii A., Bogdanov, Vyacheslav S., Magomedov, Kasim F., Mikhaylik, Elena S., Golubev, Evgenii K., Buzin, Mikhail I., Nikiforova, Galina G., Vasil'ev, Viktor G., Khrustalev, Viktor N., Dorovatovskii, Pavel V., Bakirov, Artem V., Shcherbina, Maksim А., Dzhevakov, Pavel B., Bulychev, Boris M.
Format:	Journal Article
Language:	English
Published:	Chichester Wiley Subscription Services, Inc 01-07-2021
Subjects:	catalysts Chemical synthesis Chemistry Coordination compounds Entanglement Ligands Mechanical properties Modulus of elasticity Molecular weight Molecular weight distribution Oxygen atoms Polyethylene Polymerization Polymers Titanium titanium(IV) complexes Ultra high molecular weight polyethylene ultrahigh molecular weight polyethylene Weight reduction Ziegler–Natta polymerization
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