Metal‐Organic Framework Based on an Anthracene Tetracarboxylate Ligand and Cadmium or Cobalt: Synthesis, Structure Analysis, Stability and Magnetic Properties

Metal‐organic frameworks, a class of porous polymeric materials, are presenting a development on the interface between molecular coordination chemistry and materials science and are becoming one of the hottest research topics in chemistry. Two new metal‐organic frameworks, [M’2{Co3(ACTBA)2}]n (1; M’...

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Published in:ChemistrySelect (Weinheim) Vol. 5; no. 22; pp. 6537 - 6540
Main Authors: Aleksovska, Angela, Zaake‐Hertling, Haldor, Lönnecke, Peter, Schwarze, Benedikt, Gräsing, Daniel, Matysik, Jörg, Blömer, Laura, Kersting, Berthold, Hey‐Hawkins, Evamarie
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Published: 16-06-2020
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Abstract Metal‐organic frameworks, a class of porous polymeric materials, are presenting a development on the interface between molecular coordination chemistry and materials science and are becoming one of the hottest research topics in chemistry. Two new metal‐organic frameworks, [M’2{Co3(ACTBA)2}]n (1; M’=monocation) and [(NH2Et2)2{Cd3(ACTBA)2}]n (2) (H4ACTBA=2,6,9,10‐tetrakis(p‐carboxyphenyl)anthracene), composed of trinuclear Co or Cd moieties connected by anthracene tetracarboxylate ligands are presented here, which are highly stable on removal of solvent inside the pores. The synthesis, X‐ray structure analysis, NMR spectroscopy (for 2), chemical and thermal stability, and magnetic properties (for 1) are discussed. Two Cd‐ and Co‐based metal‐organic frameworks based on a tetracarboxylate anthracene ligand were synthesized using the solvothermal approach and their properties were investigated. The trinuclear Co and Cd moieties bridged by carboxylic ligands form highly stable three‐dimensional networks that exhibit pores along the a, b and c axis.
AbstractList Metal‐organic frameworks, a class of porous polymeric materials, are presenting a development on the interface between molecular coordination chemistry and materials science and are becoming one of the hottest research topics in chemistry. Two new metal‐organic frameworks, [M’ 2 {Co 3 (ACTBA) 2 }] n ( 1 ; M’=monocation) and [(NH 2 Et 2 ) 2 {Cd 3 (ACTBA) 2 }] n ( 2 ) (H 4 ACTBA=2,6,9,10‐tetrakis( p ‐carboxyphenyl)anthracene), composed of trinuclear Co or Cd moieties connected by anthracene tetracarboxylate ligands are presented here, which are highly stable on removal of solvent inside the pores. The synthesis, X‐ray structure analysis, NMR spectroscopy (for 2 ), chemical and thermal stability, and magnetic properties (for 1 ) are discussed.
Metal‐organic frameworks, a class of porous polymeric materials, are presenting a development on the interface between molecular coordination chemistry and materials science and are becoming one of the hottest research topics in chemistry. Two new metal‐organic frameworks, [M’2{Co3(ACTBA)2}]n (1; M’=monocation) and [(NH2Et2)2{Cd3(ACTBA)2}]n (2) (H4ACTBA=2,6,9,10‐tetrakis(p‐carboxyphenyl)anthracene), composed of trinuclear Co or Cd moieties connected by anthracene tetracarboxylate ligands are presented here, which are highly stable on removal of solvent inside the pores. The synthesis, X‐ray structure analysis, NMR spectroscopy (for 2), chemical and thermal stability, and magnetic properties (for 1) are discussed. Two Cd‐ and Co‐based metal‐organic frameworks based on a tetracarboxylate anthracene ligand were synthesized using the solvothermal approach and their properties were investigated. The trinuclear Co and Cd moieties bridged by carboxylic ligands form highly stable three‐dimensional networks that exhibit pores along the a, b and c axis.
Author Matysik, Jörg
Schwarze, Benedikt
Zaake‐Hertling, Haldor
Kersting, Berthold
Gräsing, Daniel
Lönnecke, Peter
Hey‐Hawkins, Evamarie
Aleksovska, Angela
Blömer, Laura
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Snippet Metal‐organic frameworks, a class of porous polymeric materials, are presenting a development on the interface between molecular coordination chemistry and...
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SubjectTerms cadmium
cobalt
metal-organic frameworks
solvothermal synthesis
Title Metal‐Organic Framework Based on an Anthracene Tetracarboxylate Ligand and Cadmium or Cobalt: Synthesis, Structure Analysis, Stability and Magnetic Properties
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