Diphenyl ditelluride assisted synthesis of noble metal-based silver-telluride 2D organometallic nanofibers with enhanced aggregation-induced emission (AIE) after oleylamine treatment

• Published in: Dyes and pigments Vol. 220; no. C; p. 111754
• Main Authors: Djafari, Jamila, Duarte, Frederico, Fernández-Lodeiro, Javier, Fernández-Lodeiro, Adrián, Santos, Hugo, Bladt, Eva, Bals, Sara, Savvidou, Aikaterini Flessa, Balicas, Luis, Rodríguez-González, Benito, Dos Santos, Alcindo Aparecido, Capelo-Martínez, José Luis, Lodeiro, Carlos
• Format: Journal Article
• Language: English
• Published: United Kingdom Elsevier Ltd 01-12-2023; Elsevier
• Subjects: Fluorescence; Nanofiber; Oleylamine; Silver; Tellurium; Fluorescence; Silver; Nanofiber; Tellurium; Oleylamine
• ISSN: 0143-7208; 1873-3743
• DOI: 10.1016/j.dyepig.2023.111754

Silver-Telluride 2D organometallic nanofibers (NFs), using diphenyl ditelluride (DPDT) as a precursor, were synthesized. The synthesis was carried out by reacting DPDT with AgNO3 in acetonitrile at room temperature (RT) under an inert atmosphere. The resulting material was fully characterized using various techniques, including UV-VIS-NIR spectroscopy, steady-state and excited-state fluorescence spectroscopy, IR-FTIR-ATR spectroscopy, HR-ESI MS spectrometry, high-resolution transmission electron microscopy (HRTEM), BF-STEM or HAADF-STEM, confocal fluorescence microscopy images and conductivity measurements. Initially, the nanofibers were almost non-emissive. However, a remarkable modification was observed after treating the nanofibers with oleylamine under ultrasound treatment. This methodology induced an aggregation emission effect (AIE) in the solution and in the solid state, resulting in the formation of a highly red emissive fluorescent nanomaterial. This research provides valuable insights for developing new fluorescent materials with potential applications in various optical fields.
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•Diphenyl ditelluride Applications.•Nobel Metal based Silver-Telluride 2d Nanomaterials.•Fluorescent Nanothermometer Properties.•Aggregation Induced Emission (AIE).