Gold(I) and Palladium(II) Thiolato Complexes Containing Water-Soluble Phosphane Ligands

Water‐soluble gold(I) and palladium(II) complexes containing different thiolates and the phosphanes 1,3,5‐triaza‐7‐phosphaadamantane (PTA) and 3,7‐diacetyl‐1,3,7‐triaza‐5‐phosphabicyclo[3.3.1]nonane (DAPTA) are described. The complexes were characterised by spectroscopic techniques including 2D NMR...

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Bibliographic Details
Published in:	European Journal of Inorganic Chemistry Vol. 2007; no. 18; pp. 2926 - 2933
Main Authors:	Vergara, Elena, Miranda, Susana, Mohr, Fabian, Cerrada, Elena, Tiekink, Edward R. T., Romero, Pilar, Mendía, Aránzazu, Laguna, Mariano
Format:	Book Review Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 01-06-2007 WILEY‐VCH Verlag
Subjects:	Gold Palladium Phosphane ligands Thiolato complexes
Online Access:	Get full text
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Summary:	Water‐soluble gold(I) and palladium(II) complexes containing different thiolates and the phosphanes 1,3,5‐triaza‐7‐phosphaadamantane (PTA) and 3,7‐diacetyl‐1,3,7‐triaza‐5‐phosphabicyclo[3.3.1]nonane (DAPTA) are described. The complexes were characterised by spectroscopic techniques including 2D NMR experiments, and the complexes [Au(S2CNEt2)(PTA)], trans‐[Pd(SC5H4N)2(PTA)2] and trans‐[Pd(SC5H4N)2(DAPTA)2] were additionally characterised by X‐ray crystallography; the latter complex is one of the few structurally characterised DAPTA complexes. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)
Bibliography:	University of Burgos - No. BU033A06; No. 112-541A-487.01 CSIC ark:/67375/WNG-DPBS136R-H FEDER - No. CTQ2005-08099-CO3-01 istex:EE122E56695F8B3E5C43DB116AD84410ECCC1A4C Junta de Castilla y Leon ArticleID:EJIC200700112 Ministerio de Ciencia y Tecnologia (Spain)
ISSN:	1434-1948 1099-0682
DOI:	10.1002/ejic.200700112