Diamino Monosaccharide Ligands in Group 6 Carbonyl Complexes

Diamino Monosaccharide Ligands in Group 6 Carbonyl Complexes

The reaction of methyl‐2,3‐diamino‐4,6‐O‐benzylidene‐2,3‐dideoxy‐α‐D‐glucopyranoside with the hexacarbonyl complexes of chromium, molybdenum and tungsten results in three new chiral tetracarbonyl complexes containing a diamino monosaccharide ligand. They are characterized by means of 1H, 13C NMR and...

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Bibliographic Details
Published in:Zeitschrift für anorganische und allgemeine Chemie (1950) Vol. 633; no. 13-14; pp. 2395 - 2399
Main Authors: Fowelin, Christian, Matyja, Anna, Schmidt, Michael, Heck, Jürgen
Format: Journal Article
Language:English
Published: Weinheim WILEY-VCH Verlag 01-10-2007
WILEY‐VCH Verlag
Subjects:
Carbohydrates
Carbonyl ligands
Chelates
Chromium
Crystal structure
Molybdenum
N ligands
Tungsten
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Summary:The reaction of methyl‐2,3‐diamino‐4,6‐O‐benzylidene‐2,3‐dideoxy‐α‐D‐glucopyranoside with the hexacarbonyl complexes of chromium, molybdenum and tungsten results in three new chiral tetracarbonyl complexes containing a diamino monosaccharide ligand. They are characterized by means of 1H, 13C NMR and infrared spectroscopy as well as single crystal X‐ray diffraction analysis.
Bibliography:istex:4C6B2AFEE871D1E04B56ADA5F33A79711D0CEC1A
ark:/67375/WNG-MR1P68MS-9
Dedicated to Professor Dieter Fenske on the Occasion of his 65th Birthday
ArticleID:ZAAC200700331
Dedicated to Professor Dieter Fenske on the Occasion of his 65
th
Birthday
ISSN:0044-2313
1521-3749
DOI:10.1002/zaac.200700331