Polystyrene‐supported Pd(II) complex‐catalysed carboacylation of 2‐arylpyridines with alcohols via C─H bond activation under solvent‐free conditions

Polystyrene‐supported N,N‐dimethylethylenediamine Pd(II) complex C was used as an efficient catalyst for the synthesis of aromatic ketones via ortho‐acylation of sp2 C─H bonds of 2‐arylpyridines with alcohols as effective coupling partners. The alcohols were oxidized with tert‐butyl hydroperoxide to...

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Bibliographic Details
Published in:	Applied organometallic chemistry Vol. 31; no. 3; pp. np - n/a
Main Authors:	Perumgani, Pullaiah C., Parvathaneni, Sai Prathima, Keesara, Srinivas, Mandapati, Mohan Rao
Format:	Journal Article
Language:	English
Published:	Chichester Wiley Subscription Services, Inc 01-03-2017
Subjects:	Acylation Alcohol Alcohols Aldehydes Aromatic compounds Butyl hydroperoxide carboacylation Catalysts Chemical bonds Chemical synthesis Chemistry Coupling C─H activation Economic conditions Filtration Hydrogen bonds Ketones palladium(II) complex Polystyrene resins Solvents solvent‐free conditions Synthesis (chemistry)
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