Interaction of Dihydropyridines and Nucleophiles with Carbene Complexes of Chromium: Diastereo- and Enantioselective Synthesis of Polycyclic Butenolides

The interaction of N‐methyldihydropyridine with carbene complexes of chromium promotes their spontaneous homologation upon addition of a hydride to the carbene carbon and an insertion of CO. This is followed in the case of complexes tethered to a triple bond by cascade insertions of the triple bond...

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Bibliographic Details

Published in:	European journal of organic chemistry Vol. 2004; no. 11; pp. 2471 - 2502
Main Authors:	Rudler, Henri, Parlier, Andrée, Certal, Victor, Lastennet, Gabriel, Audouin, Max, Vaissermann, Jacqueline
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 01-06-2004 WILEY‐VCH Verlag
Subjects:	Butenolides Carbenes Chromium Dihydropyridines Nucleophiles
Online Access:	Get full text
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