Structural characteristics of peroxo complexes of group IV and V transition metals. Review

Structural characteristics of peroxo complexes of group IV and V transition metals. Review

Structural characteristics of peroxo complexes of transition metals of Groups IV and V (Ti, V, Nb, and Ta) with the ratios M: O2 = 1: 1, 1: 2, 1: 3, and 1: 4 and alkyl peroxo complexes of Ti, Hf, and V have been considered. The structural manifestation of the trans effect of η2-coordinated peroxo li...

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Bibliographic Details
Published in:Crystallography reports Vol. 49; no. 6; pp. 907 - 929
Main Author: Sergienko, V. S.
Format: Journal Article
Language:English
Published: New York Springer Nature B.V 01-11-2004
Subjects:
Coordination compounds
Ligands
Niobium
Titanium
Transition metals
Vanadium
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Summary:Structural characteristics of peroxo complexes of transition metals of Groups IV and V (Ti, V, Nb, and Ta) with the ratios M: O2 = 1: 1, 1: 2, 1: 3, and 1: 4 and alkyl peroxo complexes of Ti, Hf, and V have been considered. The structural manifestation of the trans effect of η2-coordinated peroxo ligand in pseudooctahedral Ti, Nb, and V monoperoxo complexes is characterized. The structural manifestations of the trans effect of multiply bonded peroxo and oxo ligands in monooxomonoperoxo complexes of vanadium(V) are compared.
ISSN:1063-7745
1562-689X
DOI:10.1134/1.1828134