Effect of Cooling Rate on Hardness and Phase Transformation of a Pd-Ag-Based Metal–Ceramic Alloy with or without Ice-Quenching

• Published in: Metals (Basel ) Vol. 11; no. 5; p. 680
• Main Authors: Shin, Hye-Jeong, Kwon, Yong-Hoon, Seol, Hyo-Joung
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 01-05-2021
• Subjects: Alloys; Ceramics; Cermets; Chemical precipitation; Cooling; Cooling effects; Cooling rate; Grain boundaries; hardness; Homogenization; Microhardness; multiple firing; Oxidation; Palladium; Pd-Ag-based alloy; Phase transitions; Porcelain; Precipitates; Prostheses; Quenching; Scanning electron microscopy; Silver; Simulation; United States > US; Japan
• ISSN: 2075-4701; 2075-4701
• DOI: 10.3390/met11050680

The aim of this study was to investigate the effect of cooling rate on the hardness and phase transformation of a Pd-Ag-based metal–ceramic alloy with or without ice-quenching. A total of 28 test specimens, in an as-cast state, were fabricated. A multiple firing simulation was performed on the randomly selected specimens (n = 3/group) in a porcelain furnace; each firing was followed by cooling at the relatively low or high cooling rate. In addition, ice-quenching after oxidation was introduced before the normal firing process (n = 3/group). Microhardness, microstructure, phase transformation and elemental distribution were observed. Oxidation followed by ice-quenching allowed the alloy to be in a homogenized state. On the other hand, the oxidation-treated specimens followed by cooling at relatively high or low cooling speeds showed much higher hardness than the ice-quenched specimen after oxidation, which was resulted from the formation of the metastable precipitates based on the InPd3 phase with tetragonal structure. The hardness of ice-quenched alloy after oxidation was recovered in the very next firing step at both the relatively high and low cooling rates. In all specimens, the Pd-rich matrix and the InPd3-based precipitates were observed. The hardness of a Pd-Ag-based metal–ceramic alloy with and without ice-quenching depended on the cooling rate during the firing process.