Strong and transparent PMMA sheet reinforced with amine functionalized BN nanoflakes for UV-shielding application

Strong and transparent PMMA sheet reinforced with amine functionalized BN nanoflakes for UV-shielding application

Polymer composites with suitable reinforcement can offer UV-shielding ability and strength simultaneously. Such material systems are being researched for many commercial applications, including window shields and automobiles. However, the inherent challenge is retaining transparency, while using rei...

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Published in:Composites. Part B, Engineering Vol. 176; p. 107274
Main Authors: Bisht, Ankita, Kumar, Vijayesh, Maity, Palash Chandra, Lahiri, Indranil, Lahiri, Debrupa
Format: Journal Article
Language:English
Published: Elsevier Ltd 01-11-2019
Subjects:
BN nanoflakes
Mechanical properties
PMMA
UV shielding
Mechanical properties
BN nanoflakes
PMMA
UV shielding
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Abstract Polymer composites with suitable reinforcement can offer UV-shielding ability and strength simultaneously. Such material systems are being researched for many commercial applications, including window shields and automobiles. However, the inherent challenge is retaining transparency, while using reinforcement for adequate strength and UV-shielding. In this study, boron-nitride nanoflakes (BN) were reinforced in poly(methyl-methacrylate) (PMMA) to synthesize a strong and transparent sheet for structures for UV-shielding purpose. BN nanoflakes were amine functionalized and added for a range of content (0.1–3 wt%). Uniform dispersion and strong interfacial interaction led to efficient load transfer from matrix to reinforcement, thus increasing strength and modulus by 155% and 148%, respectively, with 2 wt% BN. UV-B and UV-C shielding properties improved as compared to PMMA for all composition. Addition of 0.5 wt% BN to PMMA offered improvement in blocking UV-wavelength by 325%, along with high transparency of ~65% to visible light. [Display omitted]
AbstractList Polymer composites with suitable reinforcement can offer UV-shielding ability and strength simultaneously. Such material systems are being researched for many commercial applications, including window shields and automobiles. However, the inherent challenge is retaining transparency, while using reinforcement for adequate strength and UV-shielding. In this study, boron-nitride nanoflakes (BN) were reinforced in poly(methyl-methacrylate) (PMMA) to synthesize a strong and transparent sheet for structures for UV-shielding purpose. BN nanoflakes were amine functionalized and added for a range of content (0.1–3 wt%). Uniform dispersion and strong interfacial interaction led to efficient load transfer from matrix to reinforcement, thus increasing strength and modulus by 155% and 148%, respectively, with 2 wt% BN. UV-B and UV-C shielding properties improved as compared to PMMA for all composition. Addition of 0.5 wt% BN to PMMA offered improvement in blocking UV-wavelength by 325%, along with high transparency of ~65% to visible light. [Display omitted]
ArticleNumber 107274
Author Bisht, Ankita
Kumar, Vijayesh
Lahiri, Debrupa
Maity, Palash Chandra
Lahiri, Indranil
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  email: dlahifmt@iitr.ac.in
  organization: Biomaterials and Multi-Scale Mechanics Lab., Department of Metallurgical and Materials Engineering, Indian Institute of Technology Roorkee, Roorkee, 247667, Uttarakhand, India
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Snippet Polymer composites with suitable reinforcement can offer UV-shielding ability and strength simultaneously. Such material systems are being researched for many...
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StartPage 107274
SubjectTerms BN nanoflakes
Mechanical properties
PMMA
UV shielding
Title Strong and transparent PMMA sheet reinforced with amine functionalized BN nanoflakes for UV-shielding application
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