Improvement of dielectric properties of ZnO nanoparticles by Cu doping for tunable microwave devices
We report a facile chemical polyol method to synthesize Cu-doped ZnO nanoparticles with various levels of Cu. X-ray diffraction (XRD), transmission electron microscopy (TEM), and UV–Visible diffuse reflectance spectroscopy techniques were used to analyze the structural and optical properties of Zn 1...
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| Published in: | Journal of materials science. Materials in electronics Vol. 31; no. 21; pp. 18664 - 18672 |
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| Main Authors: | , , , |
| Format: | Journal Article |
| Language: | English |
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01-11-2020
Springer Nature B.V |
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| Abstract | We report a facile chemical polyol method to synthesize Cu-doped ZnO nanoparticles with various levels of Cu. X-ray diffraction (XRD), transmission electron microscopy (TEM), and UV–Visible diffuse reflectance spectroscopy techniques were used to analyze the structural and optical properties of Zn
1−
x
Cu
x
O nanoparticles. The crystallite size varies between 9.8 and 18.9 nm and decreased with the increase of Cu doping. The band energy gaps of pure and Cu-doped ZnO samples are in the range 2.5–3.1 eV. The dielectric properties, ac conductivity and impedance analysis of Zn
1−
x
Cu
x
O nanoparticles were systematically investigated. It was revealed that the doping of ZnO by Cu (with low Cu molar content) leads to obtain high dielectric constant and low tangent loss, which are very encouraging for microwave semiconductor devices. |
|---|---|
| AbstractList | We report a facile chemical polyol method to synthesize Cu-doped ZnO nanoparticles with various levels of Cu. X-ray diffraction (XRD), transmission electron microscopy (TEM), and UV–Visible diffuse reflectance spectroscopy techniques were used to analyze the structural and optical properties of Zn
1−
x
Cu
x
O nanoparticles. The crystallite size varies between 9.8 and 18.9 nm and decreased with the increase of Cu doping. The band energy gaps of pure and Cu-doped ZnO samples are in the range 2.5–3.1 eV. The dielectric properties, ac conductivity and impedance analysis of Zn
1−
x
Cu
x
O nanoparticles were systematically investigated. It was revealed that the doping of ZnO by Cu (with low Cu molar content) leads to obtain high dielectric constant and low tangent loss, which are very encouraging for microwave semiconductor devices. We report a facile chemical polyol method to synthesize Cu-doped ZnO nanoparticles with various levels of Cu. X-ray diffraction (XRD), transmission electron microscopy (TEM), and UV–Visible diffuse reflectance spectroscopy techniques were used to analyze the structural and optical properties of Zn1−xCuxO nanoparticles. The crystallite size varies between 9.8 and 18.9 nm and decreased with the increase of Cu doping. The band energy gaps of pure and Cu-doped ZnO samples are in the range 2.5–3.1 eV. The dielectric properties, ac conductivity and impedance analysis of Zn1−xCuxO nanoparticles were systematically investigated. It was revealed that the doping of ZnO by Cu (with low Cu molar content) leads to obtain high dielectric constant and low tangent loss, which are very encouraging for microwave semiconductor devices. |
| Author | Besbes, H. Bouslimi, J. Selmi, A. Fkiri, A. |
| Author_xml | – sequence: 1 givenname: A. surname: Selmi fullname: Selmi, A. email: eyman_selmi@yahoo.fr organization: Laboratory of Materials Organisation and Properties (LR99ES17), Faculty of Sciences of Tunis, University of Tunis – sequence: 2 givenname: A. surname: Fkiri fullname: Fkiri, A. organization: Lab of Hetero-Organic Compounds and Nanostructured Materials (LR18ES11), Faculty of Sciences of Bizerte, University of Carthage – sequence: 3 givenname: J. surname: Bouslimi fullname: Bouslimi, J. organization: Department of Physics, Faculty of Sciences, Taif University, Department of Engineering Physics and Instrumentation, Institute of Applied Sciences and Technology, Carthage University – sequence: 4 givenname: H. surname: Besbes fullname: Besbes, H. organization: Department of Physics, Faculty of Science, King Abdulaziz University |
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| SubjectTerms | Characterization and Evaluation of Materials Chemical synthesis Chemistry and Materials Science Crystallites Dielectric properties Doping Energy gap Materials Science Nanoparticles Optical and Electronic Materials Optical properties Semiconductor devices Zinc oxide |
| Title | Improvement of dielectric properties of ZnO nanoparticles by Cu doping for tunable microwave devices |
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