Metallocycle‐Supported POM‐Based Metal‐Organic Frameworks Assembled from Isomeric N‐Rich Ligands: Structures and Selective Adsorption and Separation of Cationic Dyes

Two novel POM‐based metal‐organic frameworks, [Ag7(L1)2·(µ2‐OH)4][H3VW12O40] (1) and [Ag8(L2)4][VW12O40]·4H2O (2) have been isolated by altering the isomeric organic ligands {5‐[n‐(1,2,4‐triazol‐4‐yl)phenyl]‐1H‐tetrazole: n = 3 (HL1); n = 4 (HL2)} under hydrothermal conditions. Due to L1 acts as a V...

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Bibliographic Details

Published in:	European journal of inorganic chemistry Vol. 2019; no. 13; pp. 1839 - 1846
Main Authors:	Liu, Lei, Zhang, Hai‐Yan, Wang, Hai‐Jun, Chen, Song, Wang, Jing‐Han, Sun, Jing‐Wen
Format:	Journal Article
Language:	English
Published:	Weinheim Wiley Subscription Services, Inc 09-04-2019
Subjects:	Cationic dyes Column chromatography Crystal Dyes separation Inorganic chemistry Ligands Metal-organic frameworks Metallocycle Polyelectrolytes Polyoxometelates Selective adsorption Tetrazoles
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