Intermediate paramagnetic centres stabilized in γ-irradiated solid hydrogen cyanide

Intermediate paramagnetic centres stabilized in γ-irradiated solid hydrogen cyanide

The low temperature radiolysis of HCN gives high yields of the paramagnetic centres CN and, mainly, H2CN radicals which upon subsequent heating to room temperature are shown to polymerise to polyene radicals.

Saved in:
Bibliographic Details
Published in:Mendeleev communications Vol. 6; no. 1; pp. 34 - 36
Main Authors: Kuzina, Svetlana I., Mozhaev, Pavel S., Kiryukhin, Dmitry P., Mikhailov, Alfa I., Barkalov, Igor M.
Format: Journal Article
Language:English
Published: Elsevier B.V 1996
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The low temperature radiolysis of HCN gives high yields of the paramagnetic centres CN and, mainly, H2CN radicals which upon subsequent heating to room temperature are shown to polymerise to polyene radicals.
ISSN:0959-9436
DOI:10.1070/MC1996v006n01ABEH000568