Bi-functional electrochromic supercapacitor based on hydrothermal-grown 3D Nb2O5 nanospheres

• Published in: Electrochimica acta Vol. 459; p. 142522
• Main Authors: Amate, Rutuja U., Morankar, Pritam J., Chavan, Ganesh T., Teli, Aviraj M., Desai, Radhika S., Dalavi, Dhanaji S., Jeon, Chan-Wook
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 10-08-2023
• Subjects: Bi-function device; Electrochromic characteristics; Energy-storage; Hydrothermal; Nanospheres; Niobium oxide; Energy-storage; Nanospheres; Niobium oxide; Hydrothermal; Electrochromic characteristics; Bi-function device
• ISSN: 0013-4686; 1873-3859
• DOI: 10.1016/j.electacta.2023.142522

•One step hydrothermal method has been adapted to synthesize Nb2O5 thin films.•Orthorhombic 3D Nb2O5 nanospheres provided more active sites for Li+ ion diffusion.•Colored state Raman provides an intervalence charge transfer reaction mechanism.•Highest coloration efficiency with energy storage capacity.•Electrochromic supercapacitor devices have lightened up a red and yellow LED.
The design and development of novel cathodic materials with suitable crystal structure and nanostructure is an essential basis for both electrochromism and electrochemical energy storage devices. In this study, Niobium oxide (Nb2O5) thin films as high-performance cathodic materials were synthesized using a facile hydrothermal method. The influence of the precursor concentration on the structural, morphological, electrochromic, and energy storage properties was investigated successfully. The X-ray diffraction analysis confirmed the highly crystalline orthorhombic nature of Nb2O5 thin films. Nanostructured Nb2O5 nanospheres effectively improved the charge transportation and mobility of charge carriers. Nb01 thin film most effectively accommodated lithium ions and facilitated the desired bifunctional performance. An electrochromic supercapacitor (ESC) of Nb01 composition showed the highest optical modulation of (76.92%), excellent reversibility of (98%), high coloration efficiency (CE) (98.75 cm2 C−1), and high-energy storage capacity (93.33 C cm−2). The fully colored ESC devices (4 × 5 cm2) have lightened a red and yellow light-emitting diode (LED) which confirms the energy storage level with the color changing ability of the 3D Nb2O5 nanospheres as a potential application in ESC.
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