Chain Dynamics in a Polyelectrolyte Solution Under Shear: A Rheological NMR Investigation
Rheological nuclear magnetic resonance (NMR) has been applied to study the effect of shear on the chain dynamics in a solution of a linear poly(sodium 4-styrenesulfonate). Information on the chain dynamics of poly(sodium 4-styrenesulfonate) sheared in a narrow-gap concentric double cylinder cell is...
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| Published in: | Applied magnetic resonance Vol. 54; no. 11-12; pp. 1533 - 1541 |
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| Abstract | Rheological nuclear magnetic resonance (NMR) has been applied to study the effect of shear on the chain dynamics in a solution of a linear poly(sodium 4-styrenesulfonate). Information on the chain dynamics of poly(sodium 4-styrenesulfonate) sheared in a narrow-gap concentric double cylinder cell is inferred from the NMR transverse relaxation
T
2
for a concentration in the semidilute-entangled and in the concentrated regime. In the semidilute-entangled concentration enhanced relaxation is observed. In the concentrated regime signatures of a loss of entanglements are seen with increasing
T
2
and a decreasing fraction of the polymer showing restricted motion. The effect is enhanced when the electrostatic interaction along the polymer chain is reduced by the addition of NaCl. |
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| AbstractList | Rheological nuclear magnetic resonance (NMR) has been applied to study the effect of shear on the chain dynamics in a solution of a linear poly(sodium 4-styrenesulfonate). Information on the chain dynamics of poly(sodium 4-styrenesulfonate) sheared in a narrow-gap concentric double cylinder cell is inferred from the NMR transverse relaxation
T
2
for a concentration in the semidilute-entangled and in the concentrated regime. In the semidilute-entangled concentration enhanced relaxation is observed. In the concentrated regime signatures of a loss of entanglements are seen with increasing
T
2
and a decreasing fraction of the polymer showing restricted motion. The effect is enhanced when the electrostatic interaction along the polymer chain is reduced by the addition of NaCl. Rheological nuclear magnetic resonance (NMR) has been applied to study the effect of shear on the chain dynamics in a solution of a linear poly(sodium 4-styrenesulfonate). Information on the chain dynamics of poly(sodium 4-styrenesulfonate) sheared in a narrow-gap concentric double cylinder cell is inferred from the NMR transverse relaxation T2 for a concentration in the semidilute-entangled and in the concentrated regime. In the semidilute-entangled concentration enhanced relaxation is observed. In the concentrated regime signatures of a loss of entanglements are seen with increasing T2 and a decreasing fraction of the polymer showing restricted motion. The effect is enhanced when the electrostatic interaction along the polymer chain is reduced by the addition of NaCl. |
| Author | Kohn, Benjamin Scheler, Ulrich Bartosch, Sascha |
| Author_xml | – sequence: 1 givenname: Sascha surname: Bartosch fullname: Bartosch, Sascha organization: Leibniz-Institut für Polymerforschung Dresden e.V – sequence: 2 givenname: Benjamin surname: Kohn fullname: Kohn, Benjamin organization: Leibniz-Institut für Polymerforschung Dresden e.V – sequence: 3 givenname: Ulrich surname: Scheler fullname: Scheler, Ulrich email: scheler@ipfdd.de organization: Leibniz-Institut für Polymerforschung Dresden e.V |
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| SubjectTerms | Atoms and Molecules in Strong Fields Chain dynamics Experiments Fourier transforms Laser Matter Interaction Molecular weight NMR Nuclear magnetic resonance Organic Chemistry Original Paper Phase transitions Physical Chemistry Physics Physics and Astronomy Polyelectrolytes Polymer melts Polymers Rheological properties Rheology Signal to noise ratio Sodium Solid State Physics Spectroscopy/Spectrometry |
| Title | Chain Dynamics in a Polyelectrolyte Solution Under Shear: A Rheological NMR Investigation |
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