Molecular sensing behavior of di-2-pyridylketone-2-thenoylhydrazone (dpktah) in non-aqueous media
Optical measurements performed on di-2-pyridylketone-2-thenoylhydrazone (dpktah) in dimethylsulfoxide (dmso) and N, N-dimethylformamide (dmf) media disclosed two intraligand charge transfer (ILCT) transitions that are sensitive to changes in their environment. Variation in the chemical surroundings...
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| Published in: | Journal of molecular structure Vol. 833; no. 1; pp. 161 - 168 |
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| Main Authors: | , |
| Format: | Journal Article |
| Language: | English |
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Elsevier B.V
15-05-2007
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| Abstract | Optical measurements performed on di-2-pyridylketone-2-thenoylhydrazone (dpktah) in dimethylsulfoxide (dmso) and
N,
N-dimethylformamide (dmf) media disclosed two intraligand charge transfer (ILCT) transitions that are sensitive to changes in their environment. Variation in the chemical surroundings of dpktah demonstrate reversible interconversion between the two conformations (α-dpktah associated with the low-energy electronic transition observed at 400
nm and β-dpktah with the electronic transition observed at 326
nm), and allowed for calculation of their extinction coefficients. Thermo-optical measurements confirmed the reversible interconversion between the α- and β-dpktah, and gave Δ
H
ø
=
−39.57, −36.58
kJ
mol
−1, Δ
S
ø
=
−145.37, +108.57
J
mol
−1, Δ
G
ø
=
+3.77, +4.22
kJ
mol
−1 and
K
=
+0.22, +0.38 at 298.15
K in dmf and dmso, respectively. The high values for the extinction coefficients, and low values for the thermodynamic parameters for the interconversion between the β- and α-forms of dpktah demonstrate the facile interconversion between the two forms and possible use of dpktah in dmf and dmso as a molecular sensor. Group 12 metal dichlorides in concentration as low as 1.00
×
10
−5
M can be detected and determined using dpktah in dmf.
1H NMR spectra measured in different solvents confirmed the sensitivity of dpktah to changes in its surroundings. At low temperatures, the spectral signature of two isomers appeared, and as the temperature increased, the spectral signature of a monomer prevails. |
|---|---|
| AbstractList | Optical measurements performed on di-2-pyridylketone-2-thenoylhydrazone (dpktah) in dimethylsulfoxide (dmso) and
N,
N-dimethylformamide (dmf) media disclosed two intraligand charge transfer (ILCT) transitions that are sensitive to changes in their environment. Variation in the chemical surroundings of dpktah demonstrate reversible interconversion between the two conformations (α-dpktah associated with the low-energy electronic transition observed at 400
nm and β-dpktah with the electronic transition observed at 326
nm), and allowed for calculation of their extinction coefficients. Thermo-optical measurements confirmed the reversible interconversion between the α- and β-dpktah, and gave Δ
H
ø
=
−39.57, −36.58
kJ
mol
−1, Δ
S
ø
=
−145.37, +108.57
J
mol
−1, Δ
G
ø
=
+3.77, +4.22
kJ
mol
−1 and
K
=
+0.22, +0.38 at 298.15
K in dmf and dmso, respectively. The high values for the extinction coefficients, and low values for the thermodynamic parameters for the interconversion between the β- and α-forms of dpktah demonstrate the facile interconversion between the two forms and possible use of dpktah in dmf and dmso as a molecular sensor. Group 12 metal dichlorides in concentration as low as 1.00
×
10
−5
M can be detected and determined using dpktah in dmf.
1H NMR spectra measured in different solvents confirmed the sensitivity of dpktah to changes in its surroundings. At low temperatures, the spectral signature of two isomers appeared, and as the temperature increased, the spectral signature of a monomer prevails. |
| Author | Gyles, Colin Bakir, Mohammed |
| Author_xml | – sequence: 1 givenname: Mohammed surname: Bakir fullname: Bakir, Mohammed email: mohammed.bakir@uwimona.edu.jm – sequence: 2 givenname: Colin surname: Gyles fullname: Gyles, Colin |
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| CitedBy_id | crossref_primary_10_1016_j_poly_2019_114111 crossref_primary_10_1016_j_molstruc_2008_12_018 crossref_primary_10_1016_j_molstruc_2010_01_005 crossref_primary_10_1016_j_poly_2017_08_017 crossref_primary_10_1016_j_molstruc_2008_07_026 crossref_primary_10_1080_00958970801993672 crossref_primary_10_1080_00958972_2017_1374379 |
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| Keywords | Di-2-pyridylketone-2-thenoylhydrazone Spectroscopy NMR Optical sensors Group 12 metal dichlorides |
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| References | Angell, Rogers, Zhang, Wolf, Jones (bib2) 2006; 250 Bakir (bib19) 1999; 466 Amendola, Esteban-Gomez, Fabbrizzi, Licchelli (bib10) 2006; 39 Bakir, Brown (bib25) 2003; 353 Liu, Lu, Ji, Zuo, You (bib5) 2006; 47 Bakir (bib28) 2002 Bakir, Abdur-Rashid (bib22) 1999; 24 Pehkonen (bib14) 1995; 120 Bakir, Gyles (bib24) 2002; 56 Wu, Wang, Zhang, Wu (bib3) 2006; 65 Basheer, Alex, George Thomas, Suresh, Das (bib4) 2006; 62 Balzani, Bandmann, Ceroni, Giansante, Hahn, Klamer, Muller, Muller, Verhaelen, Vicinelli, Vogtle (bib7) 2006; 128 Bakir, McKenzie (bib17) 1997; 425 Gaubeur, Areias, Terra, Suarez-Iha (bib13) 2002; 35 Pinto, Moreno, Garcia-Vargas (bib12) 2004; 64 Abuzuhri, Elshahawi, Kamal, Alnuri, Hannoun (bib15) 1994; 27 Carcelli, Pelizzi, Pelizzi, Mazza, Zani (bib16) 1995; 488 Gräfe, Haupt, Mohr (bib1) 2006; 565 Bakir, Corny, Green (bib30) 2005; C61 Asc, Alpdogan, Sungur (bib11) 2006; 39 Bakir (bib29) 2002; 332 Bakir, Brown (bib27) 2002; 641 Kappaun, Sovic, Stelzer, Pogantsch, Zojer, Slugovc (bib8) 2006; 4 Bakir, Brown (bib26) 2002; 609 Roncucci, Pirondini, Paderni, Massera, Dalcanale, Azov, Diederich (bib6) 2006; 12 Bakir, Gyles (bib21) 2003; 649 Wu, Zhang, Ma, Yang (bib9) 2006; 45 Bakir, Abdur-Rashid, Mulder (bib23) 2000; 51 Bakir, McKenzie (bib18) 1997 Bakir, Abdur-Rashid, Gyles (bib20) 2003; 59 Asc (10.1016/j.molstruc.2006.09.014_bib11) 2006; 39 Kappaun (10.1016/j.molstruc.2006.09.014_bib8) 2006; 4 Bakir (10.1016/j.molstruc.2006.09.014_bib30) 2005; C61 Bakir (10.1016/j.molstruc.2006.09.014_bib20) 2003; 59 Roncucci (10.1016/j.molstruc.2006.09.014_bib6) 2006; 12 Bakir (10.1016/j.molstruc.2006.09.014_bib24) 2002; 56 Bakir (10.1016/j.molstruc.2006.09.014_bib23) 2000; 51 Bakir (10.1016/j.molstruc.2006.09.014_bib28) 2002 Abuzuhri (10.1016/j.molstruc.2006.09.014_bib15) 1994; 27 Carcelli (10.1016/j.molstruc.2006.09.014_bib16) 1995; 488 Bakir (10.1016/j.molstruc.2006.09.014_bib18) 1997 Amendola (10.1016/j.molstruc.2006.09.014_bib10) 2006; 39 Bakir (10.1016/j.molstruc.2006.09.014_bib19) 1999; 466 Wu (10.1016/j.molstruc.2006.09.014_bib9) 2006; 45 Pehkonen (10.1016/j.molstruc.2006.09.014_bib14) 1995; 120 Liu (10.1016/j.molstruc.2006.09.014_bib5) 2006; 47 Bakir (10.1016/j.molstruc.2006.09.014_bib21) 2003; 649 Bakir (10.1016/j.molstruc.2006.09.014_bib25) 2003; 353 Basheer (10.1016/j.molstruc.2006.09.014_bib4) 2006; 62 Wu (10.1016/j.molstruc.2006.09.014_bib3) 2006; 65 Gaubeur (10.1016/j.molstruc.2006.09.014_bib13) 2002; 35 Bakir (10.1016/j.molstruc.2006.09.014_bib17) 1997; 425 Bakir (10.1016/j.molstruc.2006.09.014_bib29) 2002; 332 Balzani (10.1016/j.molstruc.2006.09.014_bib7) 2006; 128 Pinto (10.1016/j.molstruc.2006.09.014_bib12) 2004; 64 Gräfe (10.1016/j.molstruc.2006.09.014_bib1) 2006; 565 Bakir (10.1016/j.molstruc.2006.09.014_bib26) 2002; 609 Bakir (10.1016/j.molstruc.2006.09.014_bib27) 2002; 641 Angell (10.1016/j.molstruc.2006.09.014_bib2) 2006; 250 Bakir (10.1016/j.molstruc.2006.09.014_bib22) 1999; 24 |
| References_xml | – volume: 565 start-page: 42 year: 2006 end-page: 47 ident: bib1 publication-title: Anal. Chim. Acta contributor: fullname: Mohr – volume: 4 start-page: 1503 year: 2006 ident: bib8 publication-title: Org. Biomol. Chem. contributor: fullname: Slugovc – volume: 39 start-page: 343 year: 2006 ident: bib10 publication-title: Acc. Chem. Res. contributor: fullname: Licchelli – volume: 56 start-page: 1117 year: 2002 ident: bib24 publication-title: Talanta contributor: fullname: Gyles – volume: 353 start-page: 89 year: 2003 ident: bib25 publication-title: Inorg. Chim. Acta contributor: fullname: Brown – volume: 27 start-page: 1907 year: 1994 ident: bib15 publication-title: Anal. Lett. contributor: fullname: Hannoun – volume: 466 start-page: 60 year: 1999 ident: bib19 publication-title: J. Electroanal. Chem. contributor: fullname: Bakir – volume: 62 start-page: 605 year: 2006 end-page: 610 ident: bib4 publication-title: Tetrahedron contributor: fullname: Das – volume: 64 start-page: 562 year: 2004 ident: bib12 publication-title: Talanta contributor: fullname: Garcia-Vargas – volume: 649 start-page: 133 year: 2003 ident: bib21 publication-title: J. Mol. Struct. contributor: fullname: Gyles – volume: 488 start-page: 55 year: 1995 ident: bib16 publication-title: J. Organomet. Chem. contributor: fullname: Zani – volume: 12 start-page: 4775 year: 2006 ident: bib6 publication-title: Chem.-A Eur. J. contributor: fullname: Diederich – volume: 65 start-page: 749 year: 2006 end-page: 752 ident: bib3 publication-title: Spectrochim. Acta Part A contributor: fullname: Wu – volume: 51 start-page: 735 year: 2000 ident: bib23 publication-title: Talanta contributor: fullname: Mulder – volume: 59 start-page: 2123 year: 2003 ident: bib20 publication-title: Spectrochim. Acta Part A contributor: fullname: Gyles – start-page: 481 year: 2002 ident: bib28 publication-title: Eur. J. Inorg. Chem. contributor: fullname: Bakir – volume: 250 start-page: 1829 year: 2006 end-page: 1841 ident: bib2 publication-title: Coord. Chem. Rev. contributor: fullname: Jones – volume: 641 start-page: 183 year: 2002 ident: bib27 publication-title: J. Mol. Struct. contributor: fullname: Brown – volume: 47 start-page: 3431 year: 2006 end-page: 3434 ident: bib5 publication-title: Tetrahedron Lett. contributor: fullname: You – volume: 425 start-page: 61 year: 1997 ident: bib17 publication-title: Electroanal. Chem. contributor: fullname: McKenzie – start-page: 3571 year: 1997 ident: bib18 publication-title: J. Chem. Soc., Dalton Trans. contributor: fullname: McKenzie – volume: 39 start-page: 997 year: 2006 ident: bib11 publication-title: Anal. Lett. contributor: fullname: Sungur – volume: 128 start-page: 637 year: 2006 ident: bib7 publication-title: J. Am. Chem. Soc. contributor: fullname: Vogtle – volume: 332 start-page: 1 year: 2002 ident: bib29 publication-title: Inorg. Chim. Acta contributor: fullname: Bakir – volume: 35 start-page: 455 year: 2002 ident: bib13 publication-title: Spectrosc. Lett. contributor: fullname: Suarez-Iha – volume: 120 start-page: 2655 year: 1995 ident: bib14 publication-title: Analyst contributor: fullname: Pehkonen – volume: 609 start-page: 129 year: 2002 ident: bib26 publication-title: J. Mol. Struct. contributor: fullname: Brown – volume: 45 start-page: 3140 year: 2006 ident: bib9 publication-title: Inorg. Chem. contributor: fullname: Yang – volume: C61 start-page: o607 year: 2005 end-page: o609 ident: bib30 publication-title: Acta Cryst. contributor: fullname: Green – volume: 24 start-page: 384 year: 1999 ident: bib22 publication-title: Trans. Metal Chem. contributor: fullname: Abdur-Rashid – volume: 35 start-page: 455 year: 2002 ident: 10.1016/j.molstruc.2006.09.014_bib13 publication-title: Spectrosc. Lett. doi: 10.1081/SL-120005678 contributor: fullname: Gaubeur – volume: 4 start-page: 1503 year: 2006 ident: 10.1016/j.molstruc.2006.09.014_bib8 publication-title: Org. Biomol. Chem. doi: 10.1039/b600912c contributor: fullname: Kappaun – volume: 641 start-page: 183 year: 2002 ident: 10.1016/j.molstruc.2006.09.014_bib27 publication-title: J. Mol. Struct. doi: 10.1016/S0022-2860(02)00317-4 contributor: fullname: Bakir – volume: 27 start-page: 1907 year: 1994 ident: 10.1016/j.molstruc.2006.09.014_bib15 publication-title: Anal. Lett. doi: 10.1080/00032719408002640 contributor: fullname: Abuzuhri – volume: 488 start-page: 55 year: 1995 ident: 10.1016/j.molstruc.2006.09.014_bib16 publication-title: J. Organomet. Chem. doi: 10.1016/0022-328X(94)00003-U contributor: fullname: Carcelli – volume: 120 start-page: 2655 year: 1995 ident: 10.1016/j.molstruc.2006.09.014_bib14 publication-title: Analyst doi: 10.1039/an9952002655 contributor: fullname: Pehkonen – start-page: 481 year: 2002 ident: 10.1016/j.molstruc.2006.09.014_bib28 publication-title: Eur. J. Inorg. Chem. doi: 10.1002/1099-0682(20022)2002:2<481::AID-EJIC481>3.0.CO;2-0 contributor: fullname: Bakir – volume: 62 start-page: 605 year: 2006 ident: 10.1016/j.molstruc.2006.09.014_bib4 publication-title: Tetrahedron doi: 10.1016/j.tet.2005.10.012 contributor: fullname: Basheer – volume: 649 start-page: 133 year: 2003 ident: 10.1016/j.molstruc.2006.09.014_bib21 publication-title: J. Mol. Struct. doi: 10.1016/S0022-2860(03)00048-6 contributor: fullname: Bakir – volume: 24 start-page: 384 year: 1999 ident: 10.1016/j.molstruc.2006.09.014_bib22 publication-title: Trans. Metal Chem. doi: 10.1023/A:1006997111108 contributor: fullname: Bakir – volume: 56 start-page: 1117 year: 2002 ident: 10.1016/j.molstruc.2006.09.014_bib24 publication-title: Talanta doi: 10.1016/S0039-9140(01)00646-4 contributor: fullname: Bakir – volume: 565 start-page: 42 year: 2006 ident: 10.1016/j.molstruc.2006.09.014_bib1 publication-title: Anal. Chim. Acta doi: 10.1016/j.aca.2006.02.034 contributor: fullname: Gräfe – volume: 250 start-page: 1829 year: 2006 ident: 10.1016/j.molstruc.2006.09.014_bib2 publication-title: Coord. Chem. Rev. doi: 10.1016/j.ccr.2006.03.023 contributor: fullname: Angell – volume: 65 start-page: 749 year: 2006 ident: 10.1016/j.molstruc.2006.09.014_bib3 publication-title: Spectrochim. Acta Part A doi: 10.1016/j.saa.2006.01.009 contributor: fullname: Wu – volume: 609 start-page: 129 year: 2002 ident: 10.1016/j.molstruc.2006.09.014_bib26 publication-title: J. Mol. Struct. doi: 10.1016/S0022-2860(01)00973-5 contributor: fullname: Bakir – volume: 353 start-page: 89 year: 2003 ident: 10.1016/j.molstruc.2006.09.014_bib25 publication-title: Inorg. Chim. Acta doi: 10.1016/S0020-1693(03)00324-4 contributor: fullname: Bakir – volume: 64 start-page: 562 year: 2004 ident: 10.1016/j.molstruc.2006.09.014_bib12 publication-title: Talanta doi: 10.1016/j.talanta.2004.03.009 contributor: fullname: Pinto – volume: 51 start-page: 735 year: 2000 ident: 10.1016/j.molstruc.2006.09.014_bib23 publication-title: Talanta doi: 10.1016/S0039-9140(99)00322-7 contributor: fullname: Bakir – start-page: 3571 year: 1997 ident: 10.1016/j.molstruc.2006.09.014_bib18 publication-title: J. Chem. Soc., Dalton Trans. doi: 10.1039/a608470b contributor: fullname: Bakir – volume: 47 start-page: 3431 year: 2006 ident: 10.1016/j.molstruc.2006.09.014_bib5 publication-title: Tetrahedron Lett. doi: 10.1016/j.tetlet.2006.03.055 contributor: fullname: Liu – volume: 12 start-page: 4775 year: 2006 ident: 10.1016/j.molstruc.2006.09.014_bib6 publication-title: Chem.-A Eur. J. doi: 10.1002/chem.200600085 contributor: fullname: Roncucci – volume: 332 start-page: 1 year: 2002 ident: 10.1016/j.molstruc.2006.09.014_bib29 publication-title: Inorg. Chim. Acta doi: 10.1016/S0020-1693(02)00708-9 contributor: fullname: Bakir – volume: 425 start-page: 61 year: 1997 ident: 10.1016/j.molstruc.2006.09.014_bib17 publication-title: Electroanal. Chem. doi: 10.1016/S0022-0728(96)04940-6 contributor: fullname: Bakir – volume: 59 start-page: 2123 year: 2003 ident: 10.1016/j.molstruc.2006.09.014_bib20 publication-title: Spectrochim. Acta Part A doi: 10.1016/S1386-1425(03)00020-9 contributor: fullname: Bakir – volume: 128 start-page: 637 year: 2006 ident: 10.1016/j.molstruc.2006.09.014_bib7 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja056615j contributor: fullname: Balzani – volume: 39 start-page: 343 year: 2006 ident: 10.1016/j.molstruc.2006.09.014_bib10 publication-title: Acc. Chem. Res. doi: 10.1021/ar050195l contributor: fullname: Amendola – volume: 45 start-page: 3140 year: 2006 ident: 10.1016/j.molstruc.2006.09.014_bib9 publication-title: Inorg. Chem. doi: 10.1021/ic051589b contributor: fullname: Wu – volume: 39 start-page: 997 year: 2006 ident: 10.1016/j.molstruc.2006.09.014_bib11 publication-title: Anal. Lett. doi: 10.1080/00032710600614263 contributor: fullname: Asc – volume: C61 start-page: o607 year: 2005 ident: 10.1016/j.molstruc.2006.09.014_bib30 publication-title: Acta Cryst. contributor: fullname: Bakir – volume: 466 start-page: 60 year: 1999 ident: 10.1016/j.molstruc.2006.09.014_bib19 publication-title: J. Electroanal. Chem. doi: 10.1016/S0022-0728(99)00122-9 contributor: fullname: Bakir |
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| Snippet | Optical measurements performed on di-2-pyridylketone-2-thenoylhydrazone (dpktah) in dimethylsulfoxide (dmso) and
N,
N-dimethylformamide (dmf) media disclosed... |
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| SubjectTerms | Di-2-pyridylketone-2-thenoylhydrazone Group 12 metal dichlorides NMR Optical sensors Spectroscopy |
| Title | Molecular sensing behavior of di-2-pyridylketone-2-thenoylhydrazone (dpktah) in non-aqueous media |
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