Synthesis and spectral studies of macrocyclic Cu(II), Ni(II) and Co(II) complexes by template reaction of 1,4-bis(3-aminopropoxy)butane with metal(II) nitrate and salicylaldehyde derivatives

Six new macrocyclic complexes were synthesized by template reaction of salicylaldehyde derivatives with 1,4-bis(3-aminopropoxy)butane and metal(II) nitrate. The metal to ligand ratio of the complexes was found to be 1:1. The Cu(II) complexes are proposed to be square planar and the Ni(II) and Co(II)...

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Published in:Journal of molecular structure Vol. 891; no. 1; pp. 157 - 166
Main Authors: Ilhan, Salih, Temel, Hamdi
Format: Journal Article
Language:English
Published: Elsevier B.V 26-11-2008
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Abstract Six new macrocyclic complexes were synthesized by template reaction of salicylaldehyde derivatives with 1,4-bis(3-aminopropoxy)butane and metal(II) nitrate. The metal to ligand ratio of the complexes was found to be 1:1. The Cu(II) complexes are proposed to be square planar and the Ni(II) and Co(II) complexes are proposed to be tetrahedral geometry. Macrocyclic complexes are 1:2 electrolytes as shown by their molar conductivities ( Λ M) in DMF (dimethylformamide) of 10 −3 M solution. The structure of metal complexes is proposed from elemental analysis, FTIR, UV–vis, magnetic susceptibility measurements, molar conductivity measurements and mass spectra.
AbstractList Six new macrocyclic complexes were synthesized by template reaction of salicylaldehyde derivatives with 1,4-bis(3-aminopropoxy)butane and metal(II) nitrate. The metal to ligand ratio of the complexes was found to be 1:1. The Cu(II) complexes are proposed to be square planar and the Ni(II) and Co(II) complexes are proposed to be tetrahedral geometry. Macrocyclic complexes are 1:2 electrolytes as shown by their molar conductivities ( Λ M) in DMF (dimethylformamide) of 10 −3 M solution. The structure of metal complexes is proposed from elemental analysis, FTIR, UV–vis, magnetic susceptibility measurements, molar conductivity measurements and mass spectra.
Author Temel, Hamdi
Ilhan, Salih
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  organization: Department of Chemistry, Faculty of Education, Dicle University, Diyarbakir, Turkey
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Issue 1
Keywords Macrocyclic Schiff base
Macrocyclic Schiff base complex
1,2-Bis(2-formylphenyl)ethane or 1,3-bis(2-formylphenyl)propane
Salicylaldehyde derivatives
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Snippet Six new macrocyclic complexes were synthesized by template reaction of salicylaldehyde derivatives with 1,4-bis(3-aminopropoxy)butane and metal(II) nitrate....
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SubjectTerms 1,2-Bis(2-formylphenyl)ethane or 1,3-bis(2-formylphenyl)propane
Macrocyclic Schiff base
Macrocyclic Schiff base complex
Salicylaldehyde derivatives
Title Synthesis and spectral studies of macrocyclic Cu(II), Ni(II) and Co(II) complexes by template reaction of 1,4-bis(3-aminopropoxy)butane with metal(II) nitrate and salicylaldehyde derivatives
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