Synthesis and spectral studies of macrocyclic Cu(II), Ni(II) and Co(II) complexes by template reaction of 1,4-bis(3-aminopropoxy)butane with metal(II) nitrate and salicylaldehyde derivatives
Six new macrocyclic complexes were synthesized by template reaction of salicylaldehyde derivatives with 1,4-bis(3-aminopropoxy)butane and metal(II) nitrate. The metal to ligand ratio of the complexes was found to be 1:1. The Cu(II) complexes are proposed to be square planar and the Ni(II) and Co(II)...
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Published in: | Journal of molecular structure Vol. 891; no. 1; pp. 157 - 166 |
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Format: | Journal Article |
Language: | English |
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26-11-2008
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Abstract | Six new macrocyclic complexes were synthesized by template reaction of salicylaldehyde derivatives with 1,4-bis(3-aminopropoxy)butane and metal(II) nitrate. The metal to ligand ratio of the complexes was found to be 1:1. The Cu(II) complexes are proposed to be square planar and the Ni(II) and Co(II) complexes are proposed to be tetrahedral geometry. Macrocyclic complexes are 1:2 electrolytes as shown by their molar conductivities (
Λ
M) in DMF (dimethylformamide) of 10
−3
M solution. The structure of metal complexes is proposed from elemental analysis, FTIR, UV–vis, magnetic susceptibility measurements, molar conductivity measurements and mass spectra. |
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AbstractList | Six new macrocyclic complexes were synthesized by template reaction of salicylaldehyde derivatives with 1,4-bis(3-aminopropoxy)butane and metal(II) nitrate. The metal to ligand ratio of the complexes was found to be 1:1. The Cu(II) complexes are proposed to be square planar and the Ni(II) and Co(II) complexes are proposed to be tetrahedral geometry. Macrocyclic complexes are 1:2 electrolytes as shown by their molar conductivities (
Λ
M) in DMF (dimethylformamide) of 10
−3
M solution. The structure of metal complexes is proposed from elemental analysis, FTIR, UV–vis, magnetic susceptibility measurements, molar conductivity measurements and mass spectra. |
Author | Temel, Hamdi Ilhan, Salih |
Author_xml | – sequence: 1 givenname: Salih surname: Ilhan fullname: Ilhan, Salih email: salihilhan@dicle.edu.tr organization: Department of Chemistry, Faculty of Art and Sciences, Siirt University, Siirt, Turkey – sequence: 2 givenname: Hamdi surname: Temel fullname: Temel, Hamdi organization: Department of Chemistry, Faculty of Education, Dicle University, Diyarbakir, Turkey |
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Keywords | Macrocyclic Schiff base Macrocyclic Schiff base complex 1,2-Bis(2-formylphenyl)ethane or 1,3-bis(2-formylphenyl)propane Salicylaldehyde derivatives |
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Snippet | Six new macrocyclic complexes were synthesized by template reaction of salicylaldehyde derivatives with 1,4-bis(3-aminopropoxy)butane and metal(II) nitrate.... |
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SubjectTerms | 1,2-Bis(2-formylphenyl)ethane or 1,3-bis(2-formylphenyl)propane Macrocyclic Schiff base Macrocyclic Schiff base complex Salicylaldehyde derivatives |
Title | Synthesis and spectral studies of macrocyclic Cu(II), Ni(II) and Co(II) complexes by template reaction of 1,4-bis(3-aminopropoxy)butane with metal(II) nitrate and salicylaldehyde derivatives |
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