Structural and electrical studies of NASICON material for NOx sensing

This work reports on synthesis and properties of the sodium superionic conductor Na3.4Zr2P0.6Si2.4O12 (NASICON) prepared with the solid-state method and thick film technology. Electrochemical performance of NASICON was tested by applying it to the potentiometric NOx sensor, as a solid electrolyte. D...

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Bibliographic Details
Published in:Ceramics international Vol. 40; no. 8; pp. 12783 - 12787
Main Authors: Paściak, Grzegorz, Mielcarek, Witold, Prociów, Krystyna, Warycha, Joanna
Format: Journal Article
Language:English
Published: Elsevier Ltd 01-09-2014
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Summary:This work reports on synthesis and properties of the sodium superionic conductor Na3.4Zr2P0.6Si2.4O12 (NASICON) prepared with the solid-state method and thick film technology. Electrochemical performance of NASICON was tested by applying it to the potentiometric NOx sensor, as a solid electrolyte. Despite some potential disadvantages resulting from the route of NASICON processing, the developed sensor exhibited good performance in sensing NOx. A comparison of different methods of NASICON synthesis was made and it was concluded that the solid-state method of NASICON synthesis can still successfully compete with the alternative sol–gel route.
ISSN:0272-8842
1873-3956
DOI:10.1016/j.ceramint.2014.04.132