Highly active Ni/Co-metal organic framework bifunctional electrocatalyst for water splitting reaction

Rational design of electrocatalycally active materials with excellent performance for renewable energy conversion is of great interest. We have developed a nanosheet array of Ni/Co metal-organic framework (MOF) grown on CoO modified Ni foam (CoO/NF) substrate via the solvothermal process. The high s...

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Published in:International journal of hydrogen energy Vol. 47; no. 54; pp. 22787 - 22795
Main Authors: Van Phuc, Tran, Jana, Jayasmita, Ravi, Nivetha, Kang, Sung Gu, Chung, Jin Suk, Choi, Won Mook, Hur, Seung Hyun
Format: Journal Article
Language:English
Published: Elsevier Ltd 29-06-2022
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Abstract Rational design of electrocatalycally active materials with excellent performance for renewable energy conversion is of great interest. We have developed a nanosheet array of Ni/Co metal-organic framework (MOF) grown on CoO modified Ni foam (CoO/NF) substrate via the solvothermal process. The high surface area and low resistance of Ni/Co-MOF@CoO/NF (NC@CoO/NF) catalyst contribute to efficient water splitting. We have prepared a series of NC-n/CoO/NF (n = 1–4) catalysts to optimize the molar ratio of the Co atom in Ni MOF-74. Among them, NC-2@CoO/NF shows an excellent electrochemical performance in alkaline medium, i.e., low overpotential of 290 and 139 mV for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER), respectively. For a two-electrode system with NC-2@CoO/NF, a low cell voltage of 1.54 V at 10 mA cm−2 has been obtained for overall water splitting which is much smaller than that with commercial Ir/C– Pt/C pair. This excellent performance can be attributed to the synergistic effects of Ni/Co-MOF and CoO/NF. In addition, the as-prepared NC-2@CoO/NF exhibits excellent long-term stability. The computational simulation also supports experimental results. [Display omitted] •Highly porous Ni/Co bimetallic MOF were grown on CoO modified Ni Form.•As-synthesized catalysts showed an excellent HER and OER properties.•Computational simulation reveled the synergetic effects of Co on Ni-MOF.
AbstractList Rational design of electrocatalycally active materials with excellent performance for renewable energy conversion is of great interest. We have developed a nanosheet array of Ni/Co metal-organic framework (MOF) grown on CoO modified Ni foam (CoO/NF) substrate via the solvothermal process. The high surface area and low resistance of Ni/Co-MOF@CoO/NF (NC@CoO/NF) catalyst contribute to efficient water splitting. We have prepared a series of NC-n/CoO/NF (n = 1–4) catalysts to optimize the molar ratio of the Co atom in Ni MOF-74. Among them, NC-2@CoO/NF shows an excellent electrochemical performance in alkaline medium, i.e., low overpotential of 290 and 139 mV for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER), respectively. For a two-electrode system with NC-2@CoO/NF, a low cell voltage of 1.54 V at 10 mA cm−2 has been obtained for overall water splitting which is much smaller than that with commercial Ir/C– Pt/C pair. This excellent performance can be attributed to the synergistic effects of Ni/Co-MOF and CoO/NF. In addition, the as-prepared NC-2@CoO/NF exhibits excellent long-term stability. The computational simulation also supports experimental results. [Display omitted] •Highly porous Ni/Co bimetallic MOF were grown on CoO modified Ni Form.•As-synthesized catalysts showed an excellent HER and OER properties.•Computational simulation reveled the synergetic effects of Co on Ni-MOF.
Author Chung, Jin Suk
Choi, Won Mook
Jana, Jayasmita
Ravi, Nivetha
Kang, Sung Gu
Van Phuc, Tran
Hur, Seung Hyun
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Snippet Rational design of electrocatalycally active materials with excellent performance for renewable energy conversion is of great interest. We have developed a...
SourceID crossref
elsevier
SourceType Aggregation Database
Publisher
StartPage 22787
SubjectTerms Electrocatalyst
HER
Metal-organic framework (MOF)
OER
Water splitting
Title Highly active Ni/Co-metal organic framework bifunctional electrocatalyst for water splitting reaction
URI https://dx.doi.org/10.1016/j.ijhydene.2022.05.097
Volume 47
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