Highly active Ni/Co-metal organic framework bifunctional electrocatalyst for water splitting reaction
Rational design of electrocatalycally active materials with excellent performance for renewable energy conversion is of great interest. We have developed a nanosheet array of Ni/Co metal-organic framework (MOF) grown on CoO modified Ni foam (CoO/NF) substrate via the solvothermal process. The high s...
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Published in: | International journal of hydrogen energy Vol. 47; no. 54; pp. 22787 - 22795 |
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Main Authors: | , , , , , , |
Format: | Journal Article |
Language: | English |
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Elsevier Ltd
29-06-2022
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Abstract | Rational design of electrocatalycally active materials with excellent performance for renewable energy conversion is of great interest. We have developed a nanosheet array of Ni/Co metal-organic framework (MOF) grown on CoO modified Ni foam (CoO/NF) substrate via the solvothermal process. The high surface area and low resistance of Ni/Co-MOF@CoO/NF (NC@CoO/NF) catalyst contribute to efficient water splitting. We have prepared a series of NC-n/CoO/NF (n = 1–4) catalysts to optimize the molar ratio of the Co atom in Ni MOF-74. Among them, NC-2@CoO/NF shows an excellent electrochemical performance in alkaline medium, i.e., low overpotential of 290 and 139 mV for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER), respectively. For a two-electrode system with NC-2@CoO/NF, a low cell voltage of 1.54 V at 10 mA cm−2 has been obtained for overall water splitting which is much smaller than that with commercial Ir/C– Pt/C pair. This excellent performance can be attributed to the synergistic effects of Ni/Co-MOF and CoO/NF. In addition, the as-prepared NC-2@CoO/NF exhibits excellent long-term stability. The computational simulation also supports experimental results.
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•Highly porous Ni/Co bimetallic MOF were grown on CoO modified Ni Form.•As-synthesized catalysts showed an excellent HER and OER properties.•Computational simulation reveled the synergetic effects of Co on Ni-MOF. |
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AbstractList | Rational design of electrocatalycally active materials with excellent performance for renewable energy conversion is of great interest. We have developed a nanosheet array of Ni/Co metal-organic framework (MOF) grown on CoO modified Ni foam (CoO/NF) substrate via the solvothermal process. The high surface area and low resistance of Ni/Co-MOF@CoO/NF (NC@CoO/NF) catalyst contribute to efficient water splitting. We have prepared a series of NC-n/CoO/NF (n = 1–4) catalysts to optimize the molar ratio of the Co atom in Ni MOF-74. Among them, NC-2@CoO/NF shows an excellent electrochemical performance in alkaline medium, i.e., low overpotential of 290 and 139 mV for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER), respectively. For a two-electrode system with NC-2@CoO/NF, a low cell voltage of 1.54 V at 10 mA cm−2 has been obtained for overall water splitting which is much smaller than that with commercial Ir/C– Pt/C pair. This excellent performance can be attributed to the synergistic effects of Ni/Co-MOF and CoO/NF. In addition, the as-prepared NC-2@CoO/NF exhibits excellent long-term stability. The computational simulation also supports experimental results.
[Display omitted]
•Highly porous Ni/Co bimetallic MOF were grown on CoO modified Ni Form.•As-synthesized catalysts showed an excellent HER and OER properties.•Computational simulation reveled the synergetic effects of Co on Ni-MOF. |
Author | Chung, Jin Suk Choi, Won Mook Jana, Jayasmita Ravi, Nivetha Kang, Sung Gu Van Phuc, Tran Hur, Seung Hyun |
Author_xml | – sequence: 1 givenname: Tran orcidid: 0000-0002-1089-9684 surname: Van Phuc fullname: Van Phuc, Tran – sequence: 2 givenname: Jayasmita surname: Jana fullname: Jana, Jayasmita – sequence: 3 givenname: Nivetha surname: Ravi fullname: Ravi, Nivetha – sequence: 4 givenname: Sung Gu surname: Kang fullname: Kang, Sung Gu email: sgkang@ulsan.ac.kr – sequence: 5 givenname: Jin Suk surname: Chung fullname: Chung, Jin Suk – sequence: 6 givenname: Won Mook surname: Choi fullname: Choi, Won Mook – sequence: 7 givenname: Seung Hyun surname: Hur fullname: Hur, Seung Hyun email: shhur@ulsan.ac.kr |
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Keywords | Electrocatalyst Water splitting HER Metal-organic framework (MOF) OER |
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Title | Highly active Ni/Co-metal organic framework bifunctional electrocatalyst for water splitting reaction |
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