Hydrophilic-Hydrophobic Balance of Bis(octylethylenediamine) Zn(II), Cd(II), and Pd(II) Chlorides in Methanol/Water and Chloroform/Water Systems

Double-chained bis(N-octylethylenediamine ( = OE)) complexes, such as Zn(OE)2Cl2, Cd(OE)2Cl2, and Pd(OE)2Cl2, were prepared and their selective solubilities in water/chloroform and water/methanol solutions were studied. Although all the complexes are poorly soluble in water, they showed clearly diff...

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Bibliographic Details
Published in:Chemistry letters Vol. 29; no. 5; pp. 518 - 519
Main Authors: Iida, Masayasu, Er, Hua, Hisamatsu, Naoko, Tanase, Tomoaki
Format: Journal Article
Language:English
Published: Tokyo The Chemical Society of Japan 01-05-2000
Chemical Society of Japan
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Summary:Double-chained bis(N-octylethylenediamine ( = OE)) complexes, such as Zn(OE)2Cl2, Cd(OE)2Cl2, and Pd(OE)2Cl2, were prepared and their selective solubilities in water/chloroform and water/methanol solutions were studied. Although all the complexes are poorly soluble in water, they showed clearly different solubilities in the water/organic mixed solvents depending on each amphiphilic character.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2000.518