Silicon-tethered Heck reaction

Silicon-tethered Heck reaction

An approach to the synthesis of semicyclic dienes is described. The method employs a silicon-tethered version of the Heck reaction. A palladium catalyzed intramolecular silicon-tethered Heck reaction has been developed, which can be used for the alkenylation of five- to seven-membered rings in fair...

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Bibliographic Details
Published in:Tetrahedron letters Vol. 42; no. 2; pp. 203 - 206
Main Authors: Mayasundari, Anand, Young, David G.J.
Format: Journal Article
Language:English
Published: Elsevier Ltd 08-01-2001
Subjects:
dienes
palladium
vinyl silanes
vinylation
vinylation
palladium
vinyl silanes
dienes
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Summary:An approach to the synthesis of semicyclic dienes is described. The method employs a silicon-tethered version of the Heck reaction. A palladium catalyzed intramolecular silicon-tethered Heck reaction has been developed, which can be used for the alkenylation of five- to seven-membered rings in fair to good yield.
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(00)01910-9