A novel and convenient synthetic method for producing α-(trifluoromethyl)styrenes ( 3)

The Suzuki-type coupling reaction of arylboronic acids ( 1) with 2-bromo-3,3,3-trifluoropropene ( 2) in the presence of a catalytic amount of dichlorobis(triphenylphosphine)palladium {PdCl 2(PPh 3) 2} and a base can easily give α-(trifluoromethyl)styrenes ( 3) in good yields. It was also found that...

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Bibliographic Details

Published in:	Journal of fluorine chemistry Vol. 95; no. 1; pp. 167 - 170
Main Authors:	Pan, Rui-qi, Liu, Xing-xin, Deng, Min-zhi
Format:	Journal Article
Language:	English
Published:	Elsevier B.V 04-06-1999
Subjects:	1,2-dibromo-3,3,3-trifluoropropane 2-bromo-trifluoropropene Arylboronic acid Suzuki-type coupling α-(trifluoromethyl)styrenes 1,2-dibromo-3,3,3-trifluoropropane Suzuki-type coupling 2-bromo-trifluoropropene α-(trifluoromethyl)styrenes Arylboronic acid
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