Liquid nanostripes
Equilibrium wetting of ethanol, a volatile liquid, onto chemically patterned nanostripes has been investigated using noncontact atomic force microscopy (AFM). The chemical patterns, generated by a conducting AFM tip, are composed of COOH terminated "wetting" regions and CH3 terminated &quo...
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Published in: | Physical review letters Vol. 96; no. 5; p. 056104 |
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10-02-2006
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Abstract | Equilibrium wetting of ethanol, a volatile liquid, onto chemically patterned nanostripes has been investigated using noncontact atomic force microscopy (AFM). The chemical patterns, generated by a conducting AFM tip, are composed of COOH terminated "wetting" regions and CH3 terminated "nonwetting" regions. Controlled amounts of ethanol, from the vapor phase, condense on the COOH stripes and their shape is imaged in situ versus their width (70 < w < 300 nm). The measured profile shapes at saturation and their w(1/2) height dependence are well described by density functional theory with dispersive, nonretarded potentials. |
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AbstractList | Equilibrium wetting of ethanol, a volatile liquid, onto chemically patterned nanostripes has been investigated using noncontact atomic force microscopy (AFM). The chemical patterns, generated by a conducting AFM tip, are composed of COOH terminated "wetting" regions and CH3 terminated "nonwetting" regions. Controlled amounts of ethanol, from the vapor phase, condense on the COOH stripes and their shape is imaged in situ versus their width (70 < w < 300 nm). The measured profile shapes at saturation and their w(1/2) height dependence are well described by density functional theory with dispersive, nonretarded potentials. Equilibrium wetting of ethanol, a volatile liquid, onto chemically patterned nanostripes has been investigated using noncontact atomic force microscopy (AFM). The chemical patterns, generated by a conducting AFM tip, are composed of COOH terminated "wetting" regions and CH3 terminated "nonwetting" regions. Controlled amounts of ethanol, from the vapor phase, condense on the COOH stripes and their shape is imaged in situ versus their width (70 < w < 300 nm). The measured profile shapes at saturation and their w(1/2) height dependence are well described by density functional theory with dispersive, nonretarded potentials. |
ArticleNumber | 056104 |
Author | Checco, Antonio Ocko, Benjamin M Gang, Oleg |
Author_xml | – sequence: 1 givenname: Antonio surname: Checco fullname: Checco, Antonio organization: Condensed Matter Physics and Materials Science Department, Brookhaven National Laboratory, Upton, New York 11973, USA – sequence: 2 givenname: Oleg surname: Gang fullname: Gang, Oleg – sequence: 3 givenname: Benjamin M surname: Ocko fullname: Ocko, Benjamin M |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/16486959$$D View this record in MEDLINE/PubMed |
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Cites_doi | 10.1021/la001607w 10.1103/PhysRevLett.91.186101 10.1021/la960189l 10.1103/PhysRevB.41.1111 10.1006/jcis.1995.1121 10.1021/jp980149l 10.1103/RevModPhys.57.827 10.1103/PhysRevLett.80.1920 10.1103/PhysRevLett.66.2108 10.1103/PhysRevE.60.6919 10.1002/(SICI)1521-4095(199901)11:1<55::AID-ADMA55>3.0.CO;2-8 10.1103/PhysRevLett.85.1930 10.1021/la970948f 10.1103/PhysRevA.43.4344 10.1007/s100510050907 10.1002/adfm.200400534 10.1016/S0167-5729(02)00077-8 |
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References | PhysRevLett.96.056104Cc5R1 PhysRevLett.96.056104Cc4R1 PhysRevLett.96.056104Cc3R1 J. N. Israelachvili (PhysRevLett.96.056104Cc15R1) 1992 P. G. de Gennes (PhysRevLett.96.056104Cc1R1) 2003 PhysRevLett.96.056104Cc2R1 PhysRevLett.96.056104Cc9R1 PhysRevLett.96.056104Cc10R1 PhysRevLett.96.056104Cc8R1 PhysRevLett.96.056104Cc20R1 PhysRevLett.96.056104Cc6R1 PhysRevLett.96.056104Cc14R1 PhysRevLett.96.056104Cc13R1 PhysRevLett.96.056104Cc12R1 PhysRevLett.96.056104Cc11R1 PhysRevLett.96.056104Cc18R1 PhysRevLett.96.056104Cc17R1 PhysRevLett.96.056104Cc16R1 PhysRevLett.96.056104Cc19R1 |
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