Photolysis of dicyanodiacetylene in argon matrices

Photolysis of dicyanodiacetylene in argon matrices

Dicyanodiacetylene, NC–CC–CC–CN, was dissociated by UV irradiation of matrix-isolated species. A group of well-correlated vibrational bands was produced. Given the limited number of conceivable reactions taking place in a rigid matrix environment, and the reasonable agreement with MP2 calculatio...

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Bibliographic Details
Published in:Chemical physics letters Vol. 299; no. 2; pp. 247 - 251
Main Author: Kołos, Robert
Format: Journal Article
Language:English
Published: Elsevier B.V 06-01-1999
Online Access:Get full text
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Summary:Dicyanodiacetylene, NC–CC–CC–CN, was dissociated by UV irradiation of matrix-isolated species. A group of well-correlated vibrational bands was produced. Given the limited number of conceivable reactions taking place in a rigid matrix environment, and the reasonable agreement with MP2 calculations, one can tentatively assign these bands to cyanoisocyanodiacetylene, the simplest isomer of the parent molecule.
ISSN:0009-2614
1873-4448
DOI:10.1016/S0009-2614(98)01266-4