A mild and stereoselective synthesis of β-phosphonylacrylates

A mild and stereoselective synthesis of β-phosphonylacrylates

The addition of trimethylsilyloxy phosphorus (III) derivatives, generated in situ, to α-haloacrylates and acrylonitriles at room temperature provides a mild, general and stereoselective route to β-phosphonoacrylates. The addition of trimethylsilyloxy phosphorus (III) derivatives, generated in situ a...

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Bibliographic Details
Published in:Tetrahedron letters Vol. 39; no. 5; pp. 433 - 434
Main Authors: Afarinkia, Kamyar, Evans, Marc, Graham, Jocelyn C.H., Jimenez-Bueno, Gorka
Format: Journal Article
Language:English
Published: Elsevier Ltd 29-01-1998
Online Access:Get full text
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Summary:The addition of trimethylsilyloxy phosphorus (III) derivatives, generated in situ, to α-haloacrylates and acrylonitriles at room temperature provides a mild, general and stereoselective route to β-phosphonoacrylates. The addition of trimethylsilyloxy phosphorus (III) derivatives, generated in situ at room temperature, to α-haloacrylates and acrylonitriles provides a mild, general and stereoselective route to β-phosphonoacrylates.
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(97)10540-8