Substituted xanthylocyanines, Part IV: Trinuclear dyes with a pyronine nucleus

Substituted xanthylocyanines, Part IV: Trinuclear dyes with a pyronine nucleus

Trinuclear, dicationic and cation–anionic dyes carrying a pyronine nucleus were synthesized. Whilst their absorption spectra displayed two bands corresponding to the absorption of the cyanine and pyronine chromophores, none of the dyes fluoresced, in contrast to the parent compounds. The spectral ev...

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Published in:Dyes and pigments Vol. 77; no. 2; pp. 369 - 373
Main Authors: Shandura, M.P., Poronik, Ye. M., Kovtun, Yu. P., Ishchenko, A.A.
Format: Journal Article
Language:English
Published: Elsevier Ltd 2008
Subjects:
Biscyanine dyes
Chromophore interaction, UV–vis spectra
Xanthylium dyes
Xanthylium dyes
Biscyanine dyes
Chromophore interaction, UV–vis spectra
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Abstract Trinuclear, dicationic and cation–anionic dyes carrying a pyronine nucleus were synthesized. Whilst their absorption spectra displayed two bands corresponding to the absorption of the cyanine and pyronine chromophores, none of the dyes fluoresced, in contrast to the parent compounds. The spectral evidence suggests a significant, though not perpendicular, twist around the bond between the cyanine and pyronine moieties.
AbstractList Trinuclear, dicationic and cation–anionic dyes carrying a pyronine nucleus were synthesized. Whilst their absorption spectra displayed two bands corresponding to the absorption of the cyanine and pyronine chromophores, none of the dyes fluoresced, in contrast to the parent compounds. The spectral evidence suggests a significant, though not perpendicular, twist around the bond between the cyanine and pyronine moieties.
Author Shandura, M.P.
Ishchenko, A.A.
Kovtun, Yu. P.
Poronik, Ye. M.
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Cites_doi 10.1007/BF00128336
10.1039/jr9500002329
10.1070/RC1991v060n08ABEH001116
10.1016/j.dyepig.2005.09.026
10.1039/jr9510001024
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Keywords Xanthylium dyes
Biscyanine dyes
Chromophore interaction, UV–vis spectra
Language English
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Snippet Trinuclear, dicationic and cation–anionic dyes carrying a pyronine nucleus were synthesized. Whilst their absorption spectra displayed two bands corresponding...
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SubjectTerms Biscyanine dyes
Chromophore interaction, UV–vis spectra
Xanthylium dyes
Title Substituted xanthylocyanines, Part IV: Trinuclear dyes with a pyronine nucleus
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