Model study on the aqueous-phase hydrodechlorination of clopyralid on noble metal catalysts
The aqueous-phase catalytic hydrodechlorination (HDC) of the herbicide clopyralid was studied for the first time. The reaction was carried out on platinum- (Pt), palladium- (Pd) and gold- (Au) based mono- and bimetallic catalysts at 25 °C and atmospheric pressure using a batch reactor. Clopyralid (3...
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Published in: | Catalysis communications Vol. 14; no. 1; pp. 96 - 100 |
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Abstract | The aqueous-phase catalytic hydrodechlorination (HDC) of the herbicide clopyralid was studied for the first time. The reaction was carried out on platinum- (Pt), palladium- (Pd) and gold- (Au) based mono- and bimetallic catalysts at 25
°C and atmospheric pressure using a batch reactor. Clopyralid (3,6-dichloropyridine-2-carboxylic acid) is a systemic herbicide from the chemical class of pyridine compounds, which has a high potential to contaminate water sources. The hydrodechlorination of clopyralid (C
6H
3NO
2Cl
2) proceeds step-wise to the monochlorinated intermediates 3-chloropyridine-2-carboxylic acid and 6-chloropyridine-2-carboxylic acid (C
6H
4NO
2Cl) and to the dechlorinated intermediate picolinic acid (C
6H
5NO
2). The dechlorination is followed by hydrogenation with formation of the harmless end product pipecolinic acid (C
6H
10NO
2). With different alumina supported mono- and bimetallic catalysts a complete dechlorination and hydrogenation of clopyralid could be achieved. Pd and PdAu catalysts showed the highest activity for the dechlorination steps whereas the Pt and PtAu catalysts are most active in the complete conversion of clopyralid, i.e. combined dechlorination and hydrogenation. Summarizing, HDC is an easily applicable way to remove clopyralid from water.
► First study on the degradation of clopyralid by catalytic hydrodechlorination. ► Pd, Pt, Au mono- and bimetallic catalysts were tested. ► Degradation via dechlorination and subsequent hydrogenation to pipecolinic acid. ► PtAu catalysts are most active for dechlorination and subsequent hydrogenation. |
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AbstractList | The aqueous-phase catalytic hydrodechlorination (HDC) of the herbicide clopyralid was studied for the first time. The reaction was carried out on platinum- (Pt), palladium- (Pd) and gold- (Au) based mono- and bimetallic catalysts at 25
°C and atmospheric pressure using a batch reactor. Clopyralid (3,6-dichloropyridine-2-carboxylic acid) is a systemic herbicide from the chemical class of pyridine compounds, which has a high potential to contaminate water sources. The hydrodechlorination of clopyralid (C
6H
3NO
2Cl
2) proceeds step-wise to the monochlorinated intermediates 3-chloropyridine-2-carboxylic acid and 6-chloropyridine-2-carboxylic acid (C
6H
4NO
2Cl) and to the dechlorinated intermediate picolinic acid (C
6H
5NO
2). The dechlorination is followed by hydrogenation with formation of the harmless end product pipecolinic acid (C
6H
10NO
2). With different alumina supported mono- and bimetallic catalysts a complete dechlorination and hydrogenation of clopyralid could be achieved. Pd and PdAu catalysts showed the highest activity for the dechlorination steps whereas the Pt and PtAu catalysts are most active in the complete conversion of clopyralid, i.e. combined dechlorination and hydrogenation. Summarizing, HDC is an easily applicable way to remove clopyralid from water.
► First study on the degradation of clopyralid by catalytic hydrodechlorination. ► Pd, Pt, Au mono- and bimetallic catalysts were tested. ► Degradation via dechlorination and subsequent hydrogenation to pipecolinic acid. ► PtAu catalysts are most active for dechlorination and subsequent hydrogenation. |
Author | Vorlop, K.-D. Teevs, L. Prüße, U. |
Author_xml | – sequence: 1 givenname: L. surname: Teevs fullname: Teevs, L. – sequence: 2 givenname: K.-D. surname: Vorlop fullname: Vorlop, K.-D. – sequence: 3 givenname: U. surname: Prüße fullname: Prüße, U. email: ulf.pruesse@vti.bund.de |
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Cites_doi | 10.1002/jctb.2002 10.1016/j.apcata.2009.07.031 10.1016/S0167-2991(03)80240-9 10.1016/j.desal.2010.11.036 10.1016/j.jhazmat.2009.04.043 10.1080/03067310903096011 10.1016/j.apcata.2004.02.052 10.1021/jp065866r 10.1289/ehp.9435 10.1021/ie801462b 10.1016/S1381-1169(01)00157-1 10.1042/bj0530474 10.2298/JSC0712477A 10.3390/molecules15052994 10.1021/es048560b 10.1016/j.cattod.2010.08.010 10.1016/j.jcat.2004.05.003 10.1016/j.apcatb.2010.02.028 10.1007/s10967-011-0986-1 10.1016/j.jhazmat.2009.01.134 10.1007/s11244-009-9258-5 |
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References | Cox (bb0025) 1998; 18 Özcan, Oturan, Sahin, Oturan (bb0035) 2010; 90 Tizaoui, Mezughi, Bickley (bb0045) 2011; 273 Yamanaka, Nishikawa, Takenaka, Otsuka (bb0060) 2003; 145 Donald, Cessna, Sverko, Glozier (bb0020) 2007; 115 Nutt, Hughes, Wong (bb0100) 2005; 39 de la Fuente (bb0010) Xu, Bu, Wu, Zheng, Liu, Wang (bb0040) 2011; 288 Babu, Lingaiah, Kumar, Prasad (bb0085) 2009; 367 Legawiec-Jarzyna, Juszczyk, Bonarowska, Kaszkur, Kepinski, Kowalczyk, Karpinski (bb0125) 2009; 52 Morrison (bb0105) 1953; 53 Yuan, Keane (bb0065) 2004; 225 Wagner, Steinkämper, Biener, Schwartz (bb0110) 2010; 150 Diaz, Casas, Mohedano, Calvo, Gilarranz, Rodriguez (bb0055) 2009; 48 Wong, Alvarez, Fang, Akcin, Nutt, Miller, Heck (bb0115) 2009; 84 Sojic, Anderluh, Orcic, Abramovic (bb0005) 2009; 168 Fang, Miller, Guo, Heck, Alvarez, Wong (bb0120) 2011; 160 Abramovic, Anderluh, Sojic, Gaal (bb0015) 2007; 72 Urbano, Marinas (bb0090) 2001; 173 Prüße, Thielecke, Vorlop (bb0050) 2008 Kopinke, Mackenzie, Koehler, Georgi (bb0095) 2004; 271 Sojic, Despotovic, Abramovic, Todorova, Giannakopoulou, Trapalis (bb0030) 2010; 15 Ordonez, Vivas, Diez (bb0070) 2010; 96 Xia, Liu, Zhou, Yang, Liu, Xu, Yu, Chen, Liang (bb0080) 2009; 169 Babu, Lingaiah, Gopinath, Reddy, Prasad (bb0075) 2007; 111 Urbano (10.1016/j.catcom.2011.07.023_bb0090) 2001; 173 Wagner (10.1016/j.catcom.2011.07.023_bb0110) 2010; 150 Tizaoui (10.1016/j.catcom.2011.07.023_bb0045) 2011; 273 Donald (10.1016/j.catcom.2011.07.023_bb0020) 2007; 115 Babu (10.1016/j.catcom.2011.07.023_bb0075) 2007; 111 Sojic (10.1016/j.catcom.2011.07.023_bb0005) 2009; 168 Yuan (10.1016/j.catcom.2011.07.023_bb0065) 2004; 225 Özcan (10.1016/j.catcom.2011.07.023_bb0035) 2010; 90 de la Fuente (10.1016/j.catcom.2011.07.023_bb0010) Yamanaka (10.1016/j.catcom.2011.07.023_bb0060) 2003; 145 Fang (10.1016/j.catcom.2011.07.023_bb0120) 2011; 160 Babu (10.1016/j.catcom.2011.07.023_bb0085) 2009; 367 Kopinke (10.1016/j.catcom.2011.07.023_bb0095) 2004; 271 Wong (10.1016/j.catcom.2011.07.023_bb0115) 2009; 84 Prüße (10.1016/j.catcom.2011.07.023_bb0050) 2008 Morrison (10.1016/j.catcom.2011.07.023_bb0105) 1953; 53 Legawiec-Jarzyna (10.1016/j.catcom.2011.07.023_bb0125) 2009; 52 Abramovic (10.1016/j.catcom.2011.07.023_bb0015) 2007; 72 Diaz (10.1016/j.catcom.2011.07.023_bb0055) 2009; 48 Ordonez (10.1016/j.catcom.2011.07.023_bb0070) 2010; 96 Nutt (10.1016/j.catcom.2011.07.023_bb0100) 2005; 39 Xu (10.1016/j.catcom.2011.07.023_bb0040) 2011; 288 Cox (10.1016/j.catcom.2011.07.023_bb0025) 1998; 18 Xia (10.1016/j.catcom.2011.07.023_bb0080) 2009; 169 Sojic (10.1016/j.catcom.2011.07.023_bb0030) 2010; 15 |
References_xml | – volume: 111 start-page: 6447 year: 2007 end-page: 6453 ident: bb0075 publication-title: J. Phys. Chem. C contributor: fullname: Prasad – volume: 53 start-page: 474 year: 1953 end-page: 478 ident: bb0105 publication-title: Biochem. J. contributor: fullname: Morrison – volume: 18 start-page: 15 year: 1998 end-page: 19 ident: bb0025 publication-title: J. Pestic. Reform contributor: fullname: Cox – volume: 90 start-page: 478 year: 2010 end-page: 486 ident: bb0035 publication-title: Int. J. Environ. Anal. Chem. contributor: fullname: Oturan – volume: 96 start-page: 323 year: 2010 end-page: 328 ident: bb0070 publication-title: Appl. Catal. B: Environ. contributor: fullname: Diez – volume: 48 start-page: 3351 year: 2009 end-page: 3358 ident: bb0055 publication-title: Ind. Eng. Chem. Res. contributor: fullname: Rodriguez – volume: 168 start-page: 94 year: 2009 end-page: 101 ident: bb0005 publication-title: J. Hazard. Mater. contributor: fullname: Abramovic – start-page: 2477 year: 2008 end-page: 2500 ident: bb0050 publication-title: Handbook of Heterogeneous Catalysis contributor: fullname: Vorlop – volume: 15 start-page: 2994 year: 2010 end-page: 3009 ident: bb0030 publication-title: Molecules contributor: fullname: Trapalis – volume: 367 start-page: 70 year: 2009 end-page: 76 ident: bb0085 publication-title: Appl. Catal. A: Gen. contributor: fullname: Prasad – volume: 169 start-page: 1029 year: 2009 end-page: 1033 ident: bb0080 publication-title: J. Hazard. Mater. contributor: fullname: Liang – volume: 115 start-page: 1183 year: 2007 end-page: 1191 ident: bb0020 publication-title: Environ. Health Perspect. contributor: fullname: Glozier – volume: 72 start-page: 1477 year: 2007 end-page: 1486 ident: bb0015 publication-title: J. Serb. Chem. Soc. contributor: fullname: Gaal – volume: 173 start-page: 329 year: 2001 end-page: 345 ident: bb0090 publication-title: J. Mol. Catal. A: Chem. contributor: fullname: Marinas – volume: 160 start-page: 96 year: 2011 end-page: 102 ident: bb0120 publication-title: Catal. Today contributor: fullname: Wong – volume: 273 start-page: 197 year: 2011 end-page: 204 ident: bb0045 publication-title: Desalination contributor: fullname: Bickley – volume: 150 start-page: 400 year: 2010 ident: bb0110 publication-title: J. Biotechnol. contributor: fullname: Schwartz – volume: 84 start-page: 158 year: 2009 end-page: 166 ident: bb0115 publication-title: J. Chem. Technol. Biotechnol. contributor: fullname: Heck – volume: 39 start-page: 1346 year: 2005 end-page: 1353 ident: bb0100 publication-title: Environ. Sci. Technol. contributor: fullname: Wong – volume: 225 start-page: 510 year: 2004 end-page: 522 ident: bb0065 publication-title: J. Catal. contributor: fullname: Keane – volume: 271 start-page: 119 year: 2004 end-page: 128 ident: bb0095 publication-title: Appl. Catal. A: Gen. contributor: fullname: Georgi – volume: 52 start-page: 1037 year: 2009 end-page: 1043 ident: bb0125 publication-title: Top. Catal. contributor: fullname: Karpinski – ident: bb0010 contributor: fullname: de la Fuente – volume: 288 start-page: 759 year: 2011 end-page: 764 ident: bb0040 publication-title: J. Radioanal. Nucl. Chem. contributor: fullname: Wang – volume: 145 start-page: 383 year: 2003 end-page: 386 ident: bb0060 publication-title: Stud. Surf. Sci. Catal. contributor: fullname: Otsuka – ident: 10.1016/j.catcom.2011.07.023_bb0010 contributor: fullname: de la Fuente – volume: 84 start-page: 158 year: 2009 ident: 10.1016/j.catcom.2011.07.023_bb0115 publication-title: J. Chem. Technol. Biotechnol. doi: 10.1002/jctb.2002 contributor: fullname: Wong – volume: 367 start-page: 70 year: 2009 ident: 10.1016/j.catcom.2011.07.023_bb0085 publication-title: Appl. Catal. A: Gen. doi: 10.1016/j.apcata.2009.07.031 contributor: fullname: Babu – volume: 145 start-page: 383 year: 2003 ident: 10.1016/j.catcom.2011.07.023_bb0060 publication-title: Stud. Surf. Sci. Catal. doi: 10.1016/S0167-2991(03)80240-9 contributor: fullname: Yamanaka – volume: 273 start-page: 197 year: 2011 ident: 10.1016/j.catcom.2011.07.023_bb0045 publication-title: Desalination doi: 10.1016/j.desal.2010.11.036 contributor: fullname: Tizaoui – start-page: 2477 year: 2008 ident: 10.1016/j.catcom.2011.07.023_bb0050 contributor: fullname: Prüße – volume: 169 start-page: 1029 year: 2009 ident: 10.1016/j.catcom.2011.07.023_bb0080 publication-title: J. Hazard. Mater. doi: 10.1016/j.jhazmat.2009.04.043 contributor: fullname: Xia – volume: 90 start-page: 478 year: 2010 ident: 10.1016/j.catcom.2011.07.023_bb0035 publication-title: Int. J. Environ. Anal. Chem. doi: 10.1080/03067310903096011 contributor: fullname: Özcan – volume: 271 start-page: 119 year: 2004 ident: 10.1016/j.catcom.2011.07.023_bb0095 publication-title: Appl. Catal. A: Gen. doi: 10.1016/j.apcata.2004.02.052 contributor: fullname: Kopinke – volume: 111 start-page: 6447 year: 2007 ident: 10.1016/j.catcom.2011.07.023_bb0075 publication-title: J. Phys. Chem. C doi: 10.1021/jp065866r contributor: fullname: Babu – volume: 115 start-page: 1183 year: 2007 ident: 10.1016/j.catcom.2011.07.023_bb0020 publication-title: Environ. Health Perspect. doi: 10.1289/ehp.9435 contributor: fullname: Donald – volume: 18 start-page: 15 year: 1998 ident: 10.1016/j.catcom.2011.07.023_bb0025 publication-title: J. Pestic. Reform contributor: fullname: Cox – volume: 48 start-page: 3351 year: 2009 ident: 10.1016/j.catcom.2011.07.023_bb0055 publication-title: Ind. Eng. Chem. Res. doi: 10.1021/ie801462b contributor: fullname: Diaz – volume: 173 start-page: 329 year: 2001 ident: 10.1016/j.catcom.2011.07.023_bb0090 publication-title: J. Mol. Catal. A: Chem. doi: 10.1016/S1381-1169(01)00157-1 contributor: fullname: Urbano – volume: 53 start-page: 474 year: 1953 ident: 10.1016/j.catcom.2011.07.023_bb0105 publication-title: Biochem. J. doi: 10.1042/bj0530474 contributor: fullname: Morrison – volume: 72 start-page: 1477 year: 2007 ident: 10.1016/j.catcom.2011.07.023_bb0015 publication-title: J. Serb. Chem. Soc. doi: 10.2298/JSC0712477A contributor: fullname: Abramovic – volume: 15 start-page: 2994 year: 2010 ident: 10.1016/j.catcom.2011.07.023_bb0030 publication-title: Molecules doi: 10.3390/molecules15052994 contributor: fullname: Sojic – volume: 39 start-page: 1346 year: 2005 ident: 10.1016/j.catcom.2011.07.023_bb0100 publication-title: Environ. Sci. Technol. doi: 10.1021/es048560b contributor: fullname: Nutt – volume: 160 start-page: 96 year: 2011 ident: 10.1016/j.catcom.2011.07.023_bb0120 publication-title: Catal. Today doi: 10.1016/j.cattod.2010.08.010 contributor: fullname: Fang – volume: 225 start-page: 510 year: 2004 ident: 10.1016/j.catcom.2011.07.023_bb0065 publication-title: J. Catal. doi: 10.1016/j.jcat.2004.05.003 contributor: fullname: Yuan – volume: 96 start-page: 323 year: 2010 ident: 10.1016/j.catcom.2011.07.023_bb0070 publication-title: Appl. Catal. B: Environ. doi: 10.1016/j.apcatb.2010.02.028 contributor: fullname: Ordonez – volume: 150 start-page: 400 year: 2010 ident: 10.1016/j.catcom.2011.07.023_bb0110 publication-title: J. Biotechnol. contributor: fullname: Wagner – volume: 288 start-page: 759 year: 2011 ident: 10.1016/j.catcom.2011.07.023_bb0040 publication-title: J. Radioanal. Nucl. Chem. doi: 10.1007/s10967-011-0986-1 contributor: fullname: Xu – volume: 168 start-page: 94 year: 2009 ident: 10.1016/j.catcom.2011.07.023_bb0005 publication-title: J. Hazard. Mater. doi: 10.1016/j.jhazmat.2009.01.134 contributor: fullname: Sojic – volume: 52 start-page: 1037 year: 2009 ident: 10.1016/j.catcom.2011.07.023_bb0125 publication-title: Top. Catal. doi: 10.1007/s11244-009-9258-5 contributor: fullname: Legawiec-Jarzyna |
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Title | Model study on the aqueous-phase hydrodechlorination of clopyralid on noble metal catalysts |
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