Model study on the aqueous-phase hydrodechlorination of clopyralid on noble metal catalysts

The aqueous-phase catalytic hydrodechlorination (HDC) of the herbicide clopyralid was studied for the first time. The reaction was carried out on platinum- (Pt), palladium- (Pd) and gold- (Au) based mono- and bimetallic catalysts at 25 °C and atmospheric pressure using a batch reactor. Clopyralid (3...

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Published in:Catalysis communications Vol. 14; no. 1; pp. 96 - 100
Main Authors: Teevs, L., Vorlop, K.-D., Prüße, U.
Format: Journal Article
Language:English
Published: Elsevier B.V 25-10-2011
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Abstract The aqueous-phase catalytic hydrodechlorination (HDC) of the herbicide clopyralid was studied for the first time. The reaction was carried out on platinum- (Pt), palladium- (Pd) and gold- (Au) based mono- and bimetallic catalysts at 25 °C and atmospheric pressure using a batch reactor. Clopyralid (3,6-dichloropyridine-2-carboxylic acid) is a systemic herbicide from the chemical class of pyridine compounds, which has a high potential to contaminate water sources. The hydrodechlorination of clopyralid (C 6H 3NO 2Cl 2) proceeds step-wise to the monochlorinated intermediates 3-chloropyridine-2-carboxylic acid and 6-chloropyridine-2-carboxylic acid (C 6H 4NO 2Cl) and to the dechlorinated intermediate picolinic acid (C 6H 5NO 2). The dechlorination is followed by hydrogenation with formation of the harmless end product pipecolinic acid (C 6H 10NO 2). With different alumina supported mono- and bimetallic catalysts a complete dechlorination and hydrogenation of clopyralid could be achieved. Pd and PdAu catalysts showed the highest activity for the dechlorination steps whereas the Pt and PtAu catalysts are most active in the complete conversion of clopyralid, i.e. combined dechlorination and hydrogenation. Summarizing, HDC is an easily applicable way to remove clopyralid from water. ► First study on the degradation of clopyralid by catalytic hydrodechlorination. ► Pd, Pt, Au mono- and bimetallic catalysts were tested. ► Degradation via dechlorination and subsequent hydrogenation to pipecolinic acid. ► PtAu catalysts are most active for dechlorination and subsequent hydrogenation.
AbstractList The aqueous-phase catalytic hydrodechlorination (HDC) of the herbicide clopyralid was studied for the first time. The reaction was carried out on platinum- (Pt), palladium- (Pd) and gold- (Au) based mono- and bimetallic catalysts at 25 °C and atmospheric pressure using a batch reactor. Clopyralid (3,6-dichloropyridine-2-carboxylic acid) is a systemic herbicide from the chemical class of pyridine compounds, which has a high potential to contaminate water sources. The hydrodechlorination of clopyralid (C 6H 3NO 2Cl 2) proceeds step-wise to the monochlorinated intermediates 3-chloropyridine-2-carboxylic acid and 6-chloropyridine-2-carboxylic acid (C 6H 4NO 2Cl) and to the dechlorinated intermediate picolinic acid (C 6H 5NO 2). The dechlorination is followed by hydrogenation with formation of the harmless end product pipecolinic acid (C 6H 10NO 2). With different alumina supported mono- and bimetallic catalysts a complete dechlorination and hydrogenation of clopyralid could be achieved. Pd and PdAu catalysts showed the highest activity for the dechlorination steps whereas the Pt and PtAu catalysts are most active in the complete conversion of clopyralid, i.e. combined dechlorination and hydrogenation. Summarizing, HDC is an easily applicable way to remove clopyralid from water. ► First study on the degradation of clopyralid by catalytic hydrodechlorination. ► Pd, Pt, Au mono- and bimetallic catalysts were tested. ► Degradation via dechlorination and subsequent hydrogenation to pipecolinic acid. ► PtAu catalysts are most active for dechlorination and subsequent hydrogenation.
Author Vorlop, K.-D.
Teevs, L.
Prüße, U.
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Keywords Gold
Palladium
Clopyralid
Platinum
Hydrodechlorination
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Snippet The aqueous-phase catalytic hydrodechlorination (HDC) of the herbicide clopyralid was studied for the first time. The reaction was carried out on platinum-...
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StartPage 96
SubjectTerms Clopyralid
Gold
Hydrodechlorination
Palladium
Platinum
Title Model study on the aqueous-phase hydrodechlorination of clopyralid on noble metal catalysts
URI https://dx.doi.org/10.1016/j.catcom.2011.07.023
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