Interface engineered 2D-2D-g-C3N4/SnWO4 S-scheme heterojunction: Clioquinol degradation and dopamine sensing properties
[Display omitted] •2D-2D-g-C3N4/SnWO4 S-scheme heterojunction photocatalysts prepared.•The g-C3N4/SnWO4 samples exhibit high photocatalytic degradation of Clioquinol.•The optimum loading of g-C3N4 is 12 wt%.•12 %g-C3N4/SnWO4 displays good sensing behaviour towards dopamine.•S-scheme heterojunction m...
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Published in: | Inorganic chemistry communications Vol. 161; p. 112039 |
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Main Authors: | , , , , , , , , , , |
Format: | Journal Article |
Language: | English |
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Elsevier B.V
01-03-2024
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Abstract | [Display omitted]
•2D-2D-g-C3N4/SnWO4 S-scheme heterojunction photocatalysts prepared.•The g-C3N4/SnWO4 samples exhibit high photocatalytic degradation of Clioquinol.•The optimum loading of g-C3N4 is 12 wt%.•12 %g-C3N4/SnWO4 displays good sensing behaviour towards dopamine.•S-scheme heterojunction mechanism discussed.
A convenient and walkable protocol has been established to simplify the fabrication of surface-engineered heterojunctions between 2D/2D g-C3N4-β-SnWO4. The method involves a one-step, simultaneous thermal exfoliation-deposition technique that utilizes bulk carbon nitride and stannous tungstate in a thermal spreading process. The prepared catalysts demonstrate excellent performance in the photocatalytic decomposition of Clioquinol (a neurotoxic drug) and dopamine sensing. The results indicate that the optimal loading of carbon nitride is 12 %, with this catalyst completely decomposing clioquinol within 80 min. Lower and higher loadings result in inferior performance due to ineffective interfacial contact, the formation of a bulk-like carbon nitride phase, and the encapsulation of stannous tungstate particles, respectively. A plausible mechanism has been proposed based on scavenger studies. The 12 % g-C3N4-SnWO4 sample exhibits the lowest charge transfer resistance and demonstrates good dopamine sensing properties. The selective sensing performance has been confirmed in the presence of glucose, ascorbic acid, and urea. The limit of detection (LOD) for the 12 % g-C3N4-SnWO4 sensor system is determined to be 1.78 μM. |
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AbstractList | [Display omitted]
•2D-2D-g-C3N4/SnWO4 S-scheme heterojunction photocatalysts prepared.•The g-C3N4/SnWO4 samples exhibit high photocatalytic degradation of Clioquinol.•The optimum loading of g-C3N4 is 12 wt%.•12 %g-C3N4/SnWO4 displays good sensing behaviour towards dopamine.•S-scheme heterojunction mechanism discussed.
A convenient and walkable protocol has been established to simplify the fabrication of surface-engineered heterojunctions between 2D/2D g-C3N4-β-SnWO4. The method involves a one-step, simultaneous thermal exfoliation-deposition technique that utilizes bulk carbon nitride and stannous tungstate in a thermal spreading process. The prepared catalysts demonstrate excellent performance in the photocatalytic decomposition of Clioquinol (a neurotoxic drug) and dopamine sensing. The results indicate that the optimal loading of carbon nitride is 12 %, with this catalyst completely decomposing clioquinol within 80 min. Lower and higher loadings result in inferior performance due to ineffective interfacial contact, the formation of a bulk-like carbon nitride phase, and the encapsulation of stannous tungstate particles, respectively. A plausible mechanism has been proposed based on scavenger studies. The 12 % g-C3N4-SnWO4 sample exhibits the lowest charge transfer resistance and demonstrates good dopamine sensing properties. The selective sensing performance has been confirmed in the presence of glucose, ascorbic acid, and urea. The limit of detection (LOD) for the 12 % g-C3N4-SnWO4 sensor system is determined to be 1.78 μM. |
ArticleNumber | 112039 |
Author | Saravanan, Vadivel John, Amalraj Chutia, Bhugendra Pyarasani, Radha D. Geetha, Das Bharali, Pankaj Thrimurthulu, Gode Sumithra, Balamurugan Lakshmanan, Pandian Sivaganesh, Dhanushkodi Ramalingan, Chennan |
Author_xml | – sequence: 1 givenname: Balamurugan surname: Sumithra fullname: Sumithra, Balamurugan organization: Department of Chemistry, School of Advanced Sciences, Kalasalingam Academy of Research and Education (Deemed to be University), Krishnankoil 626126, Tamilnadu, India – sequence: 2 givenname: Vadivel surname: Saravanan fullname: Saravanan, Vadivel organization: Department of Chemistry, School of Advanced Sciences, Kalasalingam Academy of Research and Education (Deemed to be University), Krishnankoil 626126, Tamilnadu, India – sequence: 3 givenname: Chennan surname: Ramalingan fullname: Ramalingan, Chennan organization: Department of Chemistry, School of Advanced Sciences, Kalasalingam Academy of Research and Education (Deemed to be University), Krishnankoil 626126, Tamilnadu, India – sequence: 4 givenname: Pandian surname: Lakshmanan fullname: Lakshmanan, Pandian organization: Department of Chemistry, School of Advanced Sciences, Kalasalingam Academy of Research and Education (Deemed to be University), Krishnankoil 626126, Tamilnadu, India – sequence: 5 givenname: Dhanushkodi surname: Sivaganesh fullname: Sivaganesh, Dhanushkodi organization: Institute of Physics and Technology, Ural Federal University, Mira Str. 19, 620002 Yekaterinburg, Russia – sequence: 6 givenname: Bhugendra surname: Chutia fullname: Chutia, Bhugendra organization: Department of Chemical Sciences, Tezpur Central University, Assam 784028, India – sequence: 7 givenname: Pankaj surname: Bharali fullname: Bharali, Pankaj email: pankajb@tezu.ernet.in organization: Department of Chemical Sciences, Tezpur Central University, Assam 784028, India – sequence: 8 givenname: Amalraj surname: John fullname: John, Amalraj email: jamalraj@utalca.cl organization: Laboratory of Materials Science, Instituto de Quimica de Recursos Naturels, Univesidad de Talca, Casilla 747, Talca, Chile – sequence: 9 givenname: Radha D. surname: Pyarasani fullname: Pyarasani, Radha D. email: rpyarasani@ucm.cl organization: Centro de Investigacion de Estudios Avanzados del Maule (CIEAM), Vicerrectoria de Investigaciony Postgrado, Universidad Catolica de Maule, 3605 Talca, Chile – sequence: 10 givenname: Gode surname: Thrimurthulu fullname: Thrimurthulu, Gode organization: Inorganic and Physical Chemistry Division, Indian Institute of Chemical Technology, Hyderabad, Telangana 500007, India – sequence: 11 givenname: Das surname: Geetha fullname: Geetha, Das email: geetha.d@klu.ac.in organization: Department of Chemistry, School of Advanced Sciences, Kalasalingam Academy of Research and Education (Deemed to be University), Krishnankoil 626126, Tamilnadu, India |
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Keywords | Clioquinol Stannous tungstate Dopamine sensing Photocatalysis Carbon nitride S-scheme heterojunction |
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SubjectTerms | Carbon nitride Clioquinol Dopamine sensing Photocatalysis S-scheme heterojunction Stannous tungstate |
Title | Interface engineered 2D-2D-g-C3N4/SnWO4 S-scheme heterojunction: Clioquinol degradation and dopamine sensing properties |
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