Irradiation-induced effects on structure and optical properties of PbO-B2O3-Na2O glasses: γ-dosimetry application

The objective of this research is to study the impact of gamma irradiation on various PbO-B2O3-Na2O glasses that have been doped with CdO, BaO, MoO3, and WO3. The prepared glass has been experimentally examined before and after 65 kGy gamma irradiation at a dose rate of 0.799 kGy/h at 30 °C. X-ray d...

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Published in:Optical materials Vol. 137; p. 113504
Main Authors: Zakaly, Hesham M.H., Helali, Saloua, Sallam, O.I., Alrowaily, Albandari W., Elalaily, N.A., Issa, Shams A.M.
Format: Journal Article
Language:English
Published: Elsevier B.V 01-03-2023
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Abstract The objective of this research is to study the impact of gamma irradiation on various PbO-B2O3-Na2O glasses that have been doped with CdO, BaO, MoO3, and WO3. The prepared glass has been experimentally examined before and after 65 kGy gamma irradiation at a dose rate of 0.799 kGy/h at 30 °C. X-ray diffraction has been used to confirm the amorphous nature of glass samples. Structural and optical properties were studied using Infrared (IR) and UV–vis spectroscopic techniques. IR experiments of all glass samples indicate absorption bands specific to different types of borate structures. The optical characterizations such as the direct and indirect optical energy gap, index of refraction, and Fermi energy were analyzed using UV–vis spectra in the wavelength range of 190–1100 nm. We found that the values of the direct and indirect optical energy gap of these glasses are in the range of 3.57–2.81 eV and 3.27–2.45 eV, respectively. The main resonance paramagnetic centers for all prepared samples have been confirmed by the ESR spectrum. [Display omitted] •PbO-B2O5-Na2O glasses were doped with CdO, BaO, MoO3, and WO3 to improve structure-induced irradiation.•Experimentally investigated irradiation's effect on the optical properties of identical samples.•X-ray diffraction, FTIR, UV–Vis absorption, and ESR were measured before and after gamma irradiation.•Bef. and aft. Gamma-irradiation, FTIR spectra of all glass samples reveal no difference in absorption bands related to distinct forms of borate structures.•The direct and indirect optical energy gaps for glasses samples were evidenced.
AbstractList The objective of this research is to study the impact of gamma irradiation on various PbO-B2O3-Na2O glasses that have been doped with CdO, BaO, MoO3, and WO3. The prepared glass has been experimentally examined before and after 65 kGy gamma irradiation at a dose rate of 0.799 kGy/h at 30 °C. X-ray diffraction has been used to confirm the amorphous nature of glass samples. Structural and optical properties were studied using Infrared (IR) and UV–vis spectroscopic techniques. IR experiments of all glass samples indicate absorption bands specific to different types of borate structures. The optical characterizations such as the direct and indirect optical energy gap, index of refraction, and Fermi energy were analyzed using UV–vis spectra in the wavelength range of 190–1100 nm. We found that the values of the direct and indirect optical energy gap of these glasses are in the range of 3.57–2.81 eV and 3.27–2.45 eV, respectively. The main resonance paramagnetic centers for all prepared samples have been confirmed by the ESR spectrum. [Display omitted] •PbO-B2O5-Na2O glasses were doped with CdO, BaO, MoO3, and WO3 to improve structure-induced irradiation.•Experimentally investigated irradiation's effect on the optical properties of identical samples.•X-ray diffraction, FTIR, UV–Vis absorption, and ESR were measured before and after gamma irradiation.•Bef. and aft. Gamma-irradiation, FTIR spectra of all glass samples reveal no difference in absorption bands related to distinct forms of borate structures.•The direct and indirect optical energy gaps for glasses samples were evidenced.
ArticleNumber 113504
Author Helali, Saloua
Alrowaily, Albandari W.
Sallam, O.I.
Zakaly, Hesham M.H.
Elalaily, N.A.
Issa, Shams A.M.
Author_xml – sequence: 1
  givenname: Hesham M.H.
  orcidid: 0000-0002-7645-9964
  surname: Zakaly
  fullname: Zakaly, Hesham M.H.
  email: h.m.zakaly@gmail.com, h.m.zakaly@azhar.edu.eg
  organization: Physics Department, Faculty of Science, Al-Azhar University, Assiut Branch, Assiut, 71524, Egypt
– sequence: 2
  givenname: Saloua
  surname: Helali
  fullname: Helali, Saloua
  organization: Department of Physics, Faculty of Science, University of Tabuk, Tabuk, Saudi Arabia
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  givenname: O.I.
  surname: Sallam
  fullname: Sallam, O.I.
  organization: Glass Lab., Radiation Chemistry Department, National Center for Radiation Research and Technology, Egyptian Atomic Energy Authority, Egypt
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  givenname: Albandari W.
  surname: Alrowaily
  fullname: Alrowaily, Albandari W.
  organization: Department of Physics, College of Science, Princess Nourah Bint Abdulrahman University, P.O. Box 84428, Riyadh, 11671, Saudi Arabia
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  givenname: N.A.
  surname: Elalaily
  fullname: Elalaily, N.A.
  organization: Glass Lab., Radiation Chemistry Department, National Center for Radiation Research and Technology, Egyptian Atomic Energy Authority, Egypt
– sequence: 6
  givenname: Shams A.M.
  surname: Issa
  fullname: Issa, Shams A.M.
  organization: Physics Department, Faculty of Science, Al-Azhar University, Assiut Branch, Assiut, 71524, Egypt
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X-ray diffraction
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Snippet The objective of this research is to study the impact of gamma irradiation on various PbO-B2O3-Na2O glasses that have been doped with CdO, BaO, MoO3, and WO3....
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StartPage 113504
SubjectTerms ' 'Urbach's energy
Energy gap
Gamma irradiation
Infrared spectroscopy
X-ray diffraction
Title Irradiation-induced effects on structure and optical properties of PbO-B2O3-Na2O glasses: γ-dosimetry application
URI https://dx.doi.org/10.1016/j.optmat.2023.113504
Volume 137
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