Unexpected Deoxygenation of 2,2,6,6-Tetramethylpiperidine-1-Oxyl (TEMPO) by Thiyl Radicals through the Formation of Arylsulphinyl Radicals

2,2,6,6-Tetramethylpiperidine-1-oxyl (TEMPO), upon reaction with thiophenols, undergoes deoxygenation leading mainly to the formation of tetramethylpiperidinium arylsulphinates and arylsulphonates. Other identified products of the reaction are aryldisulphides, 2,2,6,6-tetramethylpiperidine, S-arylar...

Full description

Bibliographic Details

Published in:	Tetrahedron Vol. 51; no. 45; pp. 12445 - 12452
Main Authors:	Carloni, Patricia, Damiani, Elisabetta, Iacussi, Marco, Greci, Lucedio, Stipa, Pierluigi, Cauzi, Daniele, Rizzoli, Corrado, Sgarabotto, Paolo
Format:	Journal Article
Language:	English
Published:	Elsevier Ltd 06-11-1995
Online Access:	Get full text
Tags:	Add Tag No Tags, Be the first to tag this record!