Raman spectroscopic study of silver nitrate solutions in acrylonitrile at different temperatures (238–343 K)
The association between acrylonitrile (CH 2CHCN) and Ag + ion has been studied by Raman spectroscopy. The region of the ν(CN) fundamental, including the new feature attributed to cation-associated acrylonitrile, has been recorded over a temperature range 238–343 K, with concentrations between 1.0...
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Published in: | Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy Vol. 52; no. 11; pp. 1403 - 1415 |
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Language: | English |
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Elsevier B.V
01-10-1996
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Abstract | The association between acrylonitrile (CH
2CHCN) and Ag
+ ion has been studied by Raman spectroscopy. The region of the ν(CN) fundamental, including the new feature attributed to cation-associated acrylonitrile, has been recorded over a temperature range 238–343 K, with concentrations between 1.0 and 6.0
m silver ion (as silver nitrate). The wavenumber of the new band (2249 cm
−1, displaced about +20 cm
−1 from the bulk solvent CN stretching) was independent of the concentration, although a small temperature effect was detected. The evolution of the associated acrylonitrile concentration with temperature suggests a flimsy solvation sphere. The experimental results are interpreted in dynamic terms, assuming a general equilibrium between positively and negatively solvated silver ions. |
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AbstractList | The association between acrylonitrile (CH
2CHCN) and Ag
+ ion has been studied by Raman spectroscopy. The region of the ν(CN) fundamental, including the new feature attributed to cation-associated acrylonitrile, has been recorded over a temperature range 238–343 K, with concentrations between 1.0 and 6.0
m silver ion (as silver nitrate). The wavenumber of the new band (2249 cm
−1, displaced about +20 cm
−1 from the bulk solvent CN stretching) was independent of the concentration, although a small temperature effect was detected. The evolution of the associated acrylonitrile concentration with temperature suggests a flimsy solvation sphere. The experimental results are interpreted in dynamic terms, assuming a general equilibrium between positively and negatively solvated silver ions. |
Author | Alía, J.M. Edwards, H.G.M. Moore, J. |
Author_xml | – sequence: 1 givenname: J.M. surname: Alía fullname: Alía, J.M. – sequence: 2 givenname: H.G.M. surname: Edwards fullname: Edwards, H.G.M. – sequence: 3 givenname: J. surname: Moore fullname: Moore, J. |
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CitedBy_id | crossref_primary_10_1366_0003702991947865 crossref_primary_10_1016_S0924_2031_00_00073_4 crossref_primary_10_1016_S0022_2860_00_00945_5 crossref_primary_10_1021_jp0663210 crossref_primary_10_1021_jp051892y |
Cites_doi | 10.1039/f19827803263 10.1002/jrs.1250251206 10.1039/FT9969201187 10.1016/0584-8539(92)80124-F 10.1039/f19827803235 10.1366/0003702834634109 10.1016/0022-2860(95)08872-S 10.1039/f19807600244 10.1039/dc9888500269 10.1021/ja00717a009 10.1002/jrs.1250130204 10.1021/j100274a027 10.1039/f19888403517 10.1002/jrs.1250221110 10.1039/dc9776400048 10.1139/v70-198 10.1139/v89-079 10.1002/jrs.1250250732 10.1007/BF00976262 10.1002/jrs.1250250602 10.1002/jrs.1250230407 10.1039/FT9938900811 10.1021/j100715a017 10.1007/BF00650387 10.1021/j100863a030 10.1063/1.1671363 10.1002/jrs.1250260819 10.1039/FT9949000315 10.1016/0584-8539(95)01454-1 10.1007/BF00645631 10.1016/0584-8539(94)80004-9 10.1021/cr00019a014 10.1002/anie.196200541 |
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Keywords | Acrylonitrile Silver nitrate, Vibrational Raman |
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Snippet | The association between acrylonitrile (CH
2CHCN) and Ag
+ ion has been studied by Raman spectroscopy. The region of the ν(CN) fundamental, including the new... |
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SubjectTerms | Acrylonitrile Raman Silver nitrate, Vibrational |
Title | Raman spectroscopic study of silver nitrate solutions in acrylonitrile at different temperatures (238–343 K) |
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