Raman spectroscopic study of silver nitrate solutions in acrylonitrile at different temperatures (238–343 K)

The association between acrylonitrile (CH 2CHCN) and Ag + ion has been studied by Raman spectroscopy. The region of the ν(CN) fundamental, including the new feature attributed to cation-associated acrylonitrile, has been recorded over a temperature range 238–343 K, with concentrations between 1.0...

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Published in:Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy Vol. 52; no. 11; pp. 1403 - 1415
Main Authors: Alía, J.M., Edwards, H.G.M., Moore, J.
Format: Journal Article
Language:English
Published: Elsevier B.V 01-10-1996
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Abstract The association between acrylonitrile (CH 2CHCN) and Ag + ion has been studied by Raman spectroscopy. The region of the ν(CN) fundamental, including the new feature attributed to cation-associated acrylonitrile, has been recorded over a temperature range 238–343 K, with concentrations between 1.0 and 6.0 m silver ion (as silver nitrate). The wavenumber of the new band (2249 cm −1, displaced about +20 cm −1 from the bulk solvent CN stretching) was independent of the concentration, although a small temperature effect was detected. The evolution of the associated acrylonitrile concentration with temperature suggests a flimsy solvation sphere. The experimental results are interpreted in dynamic terms, assuming a general equilibrium between positively and negatively solvated silver ions.
AbstractList The association between acrylonitrile (CH 2CHCN) and Ag + ion has been studied by Raman spectroscopy. The region of the ν(CN) fundamental, including the new feature attributed to cation-associated acrylonitrile, has been recorded over a temperature range 238–343 K, with concentrations between 1.0 and 6.0 m silver ion (as silver nitrate). The wavenumber of the new band (2249 cm −1, displaced about +20 cm −1 from the bulk solvent CN stretching) was independent of the concentration, although a small temperature effect was detected. The evolution of the associated acrylonitrile concentration with temperature suggests a flimsy solvation sphere. The experimental results are interpreted in dynamic terms, assuming a general equilibrium between positively and negatively solvated silver ions.
Author Alía, J.M.
Edwards, H.G.M.
Moore, J.
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Keywords Acrylonitrile
Silver nitrate, Vibrational
Raman
Language English
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Snippet The association between acrylonitrile (CH 2CHCN) and Ag + ion has been studied by Raman spectroscopy. The region of the ν(CN) fundamental, including the new...
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SubjectTerms Acrylonitrile
Raman
Silver nitrate, Vibrational
Title Raman spectroscopic study of silver nitrate solutions in acrylonitrile at different temperatures (238–343 K)
URI https://dx.doi.org/10.1016/0584-8539(96)01705-9
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