Parameters affecting transition temperatures of poly(lactic acid-co-polydiols) copolymer-based polyester urethanes and their shape memory behavior

A series of polyester urethanes (PEUs) comprising poly(lactic acid‐co‐polydiol) copolymers as a soft segment, 4,4′‐diphenylmethane diisocyanate (MDI) and 1,4‐butanediol (BDO) as a hard segment were systematically synthesized. Soft segments, which were block copolymers of L‐lactide (LA) and polydiols...

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Published in:	Polymers for advanced technologies Vol. 23; no. 8; pp. 1166 - 1173
Main Authors:	Petchsuk, A., Klinsukhon, W., Sirikittikul, D., Prahsarn, C.
Format:	Journal Article
Language:	English
Published:	Hoboken Wiley Subscription Services, Inc., A Wiley Company 01-08-2012
Subjects:	poly(ethylene glycol) poly(lactic acid-co-polydiol) poly(trimethylene ether glycol) polyester urethane shape memory
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Abstract	A series of polyester urethanes (PEUs) comprising poly(lactic acid‐co‐polydiol) copolymers as a soft segment, 4,4′‐diphenylmethane diisocyanate (MDI) and 1,4‐butanediol (BDO) as a hard segment were systematically synthesized. Soft segments, which were block copolymers of L‐lactide (LA) and polydiols such as poly(ethylene glycol) and poly(trimethylene ether glycol), were prepared via ring opening polymerization. Glass transition temperatures (Tg) of the obtained PEUs were found strongly dependent on properties of copolymer soft segments. By simply changing composition ratio, type and molecular weight of polydiols in the soft segment preparation step, Tg of PEU can be varied in the broad range of 0–57°C. The synthesized PEUs exhibited shape memory behavior at their transition temperatures. PEUs with hard segment ratio higher than 65 mole percent showed good shape recovery. These findings suggested that it is important to manipulate molecular structure of the copolymer soft segment for a desirable transition temperature and design optimal soft to hard segment ratio in PEU for good shape recovery. Copyright © 2011 John Wiley & Sons, Ltd.
AbstractList	A series of polyester urethanes (PEUs) comprising poly(lactic acid‐co‐polydiol) copolymers as a soft segment, 4,4′‐diphenylmethane diisocyanate (MDI) and 1,4‐butanediol (BDO) as a hard segment were systematically synthesized. Soft segments, which were block copolymers of L‐lactide (LA) and polydiols such as poly(ethylene glycol) and poly(trimethylene ether glycol), were prepared via ring opening polymerization. Glass transition temperatures (Tg) of the obtained PEUs were found strongly dependent on properties of copolymer soft segments. By simply changing composition ratio, type and molecular weight of polydiols in the soft segment preparation step, Tg of PEU can be varied in the broad range of 0–57°C. The synthesized PEUs exhibited shape memory behavior at their transition temperatures. PEUs with hard segment ratio higher than 65 mole percent showed good shape recovery. These findings suggested that it is important to manipulate molecular structure of the copolymer soft segment for a desirable transition temperature and design optimal soft to hard segment ratio in PEU for good shape recovery. Copyright © 2011 John Wiley & Sons, Ltd. A series of polyester urethanes (PEUs) comprising poly(lactic acid‐co‐polydiol) copolymers as a soft segment, 4,4′‐diphenylmethane diisocyanate (MDI) and 1,4‐butanediol (BDO) as a hard segment were systematically synthesized. Soft segments, which were block copolymers of L ‐lactide (LA) and polydiols such as poly(ethylene glycol) and poly(trimethylene ether glycol), were prepared via ring opening polymerization. Glass transition temperatures ( T g ) of the obtained PEUs were found strongly dependent on properties of copolymer soft segments. By simply changing composition ratio, type and molecular weight of polydiols in the soft segment preparation step, T g of PEU can be varied in the broad range of 0–57°C. The synthesized PEUs exhibited shape memory behavior at their transition temperatures. PEUs with hard segment ratio higher than 65 mole percent showed good shape recovery. These findings suggested that it is important to manipulate molecular structure of the copolymer soft segment for a desirable transition temperature and design optimal soft to hard segment ratio in PEU for good shape recovery. Copyright © 2011 John Wiley & Sons, Ltd.
Author	Prahsarn, C. Petchsuk, A. Klinsukhon, W. Sirikittikul, D.
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Cites_doi	10.1016/j.polymer.2006.12.051 10.1126/science.1066102 10.1002/pat.624 10.1021/ma001842l 10.1002/1521-3773(20020617)41:12<2034::AID-ANIE2034>3.0.CO;2-M 10.1016/S1369-7021(07)70047-0 10.1016/S0032-3861(01)00606-1 10.1016/j.matchemphys.2005.09.065 10.1016/j.polymer.2007.06.032 10.1016/j.eurpolymj.2005.11.029 10.1016/j.matdes.2010.02.008 10.1016/S0032-3861(96)00442-9 10.1007/BF03218717
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References	Y. Zhuohong, H. Jinlian, L. Yeqiu, Y. Lapyan, Mater. Chem. Phys. 2006; 98, 368-372. D. K. Yoo, D. Kim, Macromol. Res. 2006; 510. H. Balakrishnan, A. Hassan, M. U. Wahit, A. A. Yussuf, S. B. A. Razak, Mater. Des. 2010; 31, 3289. A. Lendlein, R. Langer, Science 2002; 296, 1673. C. Min, W. Cui, J. Bei, S. Wang, Polym. Adv. Technol. 2005; 16, 608. M. Behl, A. Lendlein, Mater. Today 2007; 10, 20. C. P. Buckley, C. Prisacariu, A. Caraculacu, Polymer 2007; 48, 1388. W. Wang, P. Ping, X. Chen, X. Jing, Eur. Polym. J. 2006; 42, 1240. B. K. Kim, S. Y. Lee, M. Xu, Polymer 1996; 37, 5781. F. L. Ji, J. L. Hu, T. C. Li, Y. W. Wong, Polymer 2007; 48, 5133. B. S. Lee, B. C. Chun, Y-C. Chung, K. I. Sul, J. W. Cho, Macromolecules 2001; 34, 6431. J. Tuominen, J. Kylmae, J. Seppaelae, Polymer 2002; 43, 3. A. Lendlein, S. Kelch, Angew. Chem. Int. Ed. 2002; 41, 2034. 2010; 31 2006; 42 2002; 296 2002; 41 2006; 98 2002; 43 2007 2006 2007; 10 2001; 34 2005; 16 1996; 37 2007; 48 e_1_2_6_8_2 e_1_2_6_7_2 e_1_2_6_9_2 e_1_2_6_4_2 e_1_2_6_3_2 e_1_2_6_6_2 e_1_2_6_5_2 e_1_2_6_12_2 e_1_2_6_13_2 e_1_2_6_2_2 e_1_2_6_10_2 e_1_2_6_11_2 e_1_2_6_14_2 e_1_2_6_15_2
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SubjectTerms	poly(ethylene glycol) poly(lactic acid-co-polydiol) poly(trimethylene ether glycol) polyester urethane shape memory
Title	Parameters affecting transition temperatures of poly(lactic acid-co-polydiols) copolymer-based polyester urethanes and their shape memory behavior
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