A Cadmium Anionic 1-D Coordination Polymer {[Cd(H2O)6][Cd2(atr)2(μ2-btc)2(H2O)4] 2H2O}n within a 3-D Supramolecular Charge-Assisted Hydrogen-Bonded and π-Stacking Network

The hydrothermal reaction of 4,4'-bis(1,2,4-triazol-4-yl) (btr) and benzene-1,3,5-tricarboxylic acid (H3btc) with Cd(OAc)2 times 2H2O at 125 degree C in situ forms 4-amino-1,2,4-triazole (atr) from btr, which crystallizes to a mixed-ligand, poly-anionic chain of [Cd2(atr)2( mu 2-btc)2(H2O)4]2-....

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Bibliographic Details

Published in:	Crystals (Basel) Vol. 6; no. 3; p. 23
Main Authors:	Tahli, Anas, Köc, Ümit, Elshaarawy, Reda, Kautz, Anna, Janiak, Christoph
Format:	Journal Article
Language:	English
Published:	MDPI AG 01-03-2016
Subjects:	anionic coordination polymer Cadmium charge-assisted H-bonds Coordination polymers crystal engineering Crystallization Crystals Hydrogen bonding Hydrogen bonds hydrogen-bonded network Networks Three dimensional
Online Access:	Get full text
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