Liquidus Projection Surface and Isothermal Section at 1200 °C of Ni-Ru-Y
Scanning electron microscopy studies with energy dispersive x-ray analyses of as-cast and annealed samples of Ni-Ru-Y were used to produce a solidification projection, a liquidus projection surface and an isothermal section at 1200 °C. The ~YNi 2 , ~YNi 3 and ~YRu 2 phases had wider solubilities tha...
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| Published in: | Journal of phase equilibria and diffusion Vol. 36; no. 2; pp. 149 - 168 |
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| Main Authors: | , , , |
| Format: | Journal Article |
| Language: | English |
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01-04-2015
Springer Nature B.V |
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| Abstract | Scanning electron microscopy studies with energy dispersive x-ray analyses of as-cast and annealed samples of Ni-Ru-Y were used to produce a solidification projection, a liquidus projection surface and an isothermal section at 1200 °C. The ~YNi
2
, ~YNi
3
and ~YRu
2
phases had wider solubilities than line compounds, and also extended the furthest into the system. The binary phase extensions into the ternary were: ~51 at.% Ru for ~YNi
2
; ~22 at.% Ru for ~YNi
3
; ~13 at.% Ru for ~YNi
5
; ~7 at.% Ru for ~YNi; ~12 at.% Ni for ~YRu
2
and ~10 at.% for ~Y
44
Ru
25
. Ruthenium stabilised ~YNi
2
, so that it solidified at a higher temperature in the ternary than in the Ni-Y binary. A ternary phase was confirmed at Y
51
Ru
15
Ni
34
(at.%), which forms in a peritectic reaction. The ~Y
3
Ru and ~Y
3
Ni phases were isomorphous and formed a continuous solid solution. Heat treatment at 1200 °C gave the phases: (Ru), ~YRu
2
, ~YNi
2
, ~YNi
3
, ~YNi
4
, ~YNi
5
and (Y). |
|---|---|
| AbstractList | Scanning electron microscopy studies with energy dispersive x-ray analyses of as-cast and annealed samples of Ni-Ru-Y were used to produce a solidification projection, a liquidus projection surface and an isothermal section at 1200 °C. The ~YNi
2
, ~YNi
3
and ~YRu
2
phases had wider solubilities than line compounds, and also extended the furthest into the system. The binary phase extensions into the ternary were: ~51 at.% Ru for ~YNi
2
; ~22 at.% Ru for ~YNi
3
; ~13 at.% Ru for ~YNi
5
; ~7 at.% Ru for ~YNi; ~12 at.% Ni for ~YRu
2
and ~10 at.% for ~Y
44
Ru
25
. Ruthenium stabilised ~YNi
2
, so that it solidified at a higher temperature in the ternary than in the Ni-Y binary. A ternary phase was confirmed at Y
51
Ru
15
Ni
34
(at.%), which forms in a peritectic reaction. The ~Y
3
Ru and ~Y
3
Ni phases were isomorphous and formed a continuous solid solution. Heat treatment at 1200 °C gave the phases: (Ru), ~YRu
2
, ~YNi
2
, ~YNi
3
, ~YNi
4
, ~YNi
5
and (Y). Scanning electron microscopy studies with energy dispersive x-ray analyses of as-cast and annealed samples of Ni-Ru-Y were used to produce a solidification projection, a liquidus projection surface and an isothermal section at 1200 °C. The ~YNi^sub 2^, ~YNi^sub 3^ and ~YRu^sub 2^ phases had wider solubilities than line compounds, and also extended the furthest into the system. The binary phase extensions into the ternary were: ~51 at.% Ru for ~YNi^sub 2^; ~22 at.% Ru for ~YNi^sub 3^; ~13 at.% Ru for ~YNi^sub 5^; ~7 at.% Ru for ~YNi; ~12 at.% Ni for ~YRu^sub 2^ and ~10 at.% for ~Y^sub 44^Ru^sub 25^. Ruthenium stabilised ~YNi^sub 2^, so that it solidified at a higher temperature in the ternary than in the Ni-Y binary. A ternary phase was confirmed at Y^sub 51^Ru^sub 15^Ni^sub 34^ (at.%), which forms in a peritectic reaction. The ~Y^sub 3^Ru and ~Y^sub 3^Ni phases were isomorphous and formed a continuous solid solution. Heat treatment at 1200 °C gave the phases: (Ru), ~YRu^sub 2^, ~YNi^sub 2^, ~YNi^sub 3^, ~YNi^sub 4^, ~YNi^sub 5^ and (Y). |
| Author | Jain, P. K. Cornish, L. A. Coetzee, S. H. Witcomb, M. J. |
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| Keywords | energy dispersive spectrometry (EDS) scanning electron microscopy (SEM) liquidus surface projection Ni-Ru-Y ternary phase diagram isothermal section 1200 °C |
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| Snippet | Scanning electron microscopy studies with energy dispersive x-ray analyses of as-cast and annealed samples of Ni-Ru-Y were used to produce a solidification... |
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| SubjectTerms | Ceramics Composites Crystallography and Scattering Methods Engineering Thermodynamics Glass Heat and Mass Transfer Metallic Materials Natural Materials Physics Physics and Astronomy Thermodynamics |
| Title | Liquidus Projection Surface and Isothermal Section at 1200 °C of Ni-Ru-Y |
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